Laboratoire Interuniversitaire des Systèmes Atmosphériques, UMR-CNRS 7583, Université Paris-Est et Université Paris Diderot, Institut Pierre Simon Laplace (IPSL), Créteil, France.
J Phys Chem A. 2010 Sep 23;114(37):10045-8. doi: 10.1021/jp103992f.
Knowing the ozone absorption cross sections in the ultraviolet and infrared spectral range, with an accuracy of better than 1%, is of the utmost importance for atmospheric remote-sensing applications. For this reason, various ozone intensity intercomparisons and measurements have been published these last years. However, the corresponding results proved not to be consistent and thus have raised a controversial discussion in the community of atmospheric remote-sensing. This study, where great care has been taken to avoid any possible error, reports a new laboratory intercomparison of the ozone absorption coefficients in the mid-infrared (10 μm) and ultraviolet (300-350 nm) spectral regions. It gives a new piece of information to the puzzling problem concerning the ozone IR and UV cross sections and confirms that the IR and UV cross sections recommended in the literature are in disagreement of about 4%.
了解紫外线和红外线光谱范围内臭氧吸收截面的精确值(优于 1%),对大气遥感应用至关重要。出于这个原因,近年来已经发表了各种臭氧强度比较和测量。然而,相应的结果并不一致,因此在大气遥感领域引起了争议。本研究在避免任何可能的误差方面非常谨慎,报告了中红外(10μm)和紫外(300-350nm)光谱区域臭氧吸收系数的新实验室比较。这为臭氧红外和紫外截面的令人费解的问题提供了新的信息,并证实文献中推荐的红外和紫外截面之间存在约 4%的差异。