羧酸衍生二吡咯用于形成六核铱/铜桨轮配合物。
Carboxylic acid appended dipyrrin for the formation of a hexanuclear iridium/copper paddlewheel complex.
机构信息
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, F-67000 Strasbourg, France.
出版信息
Inorg Chem. 2010 Oct 4;49(19):8659-61. doi: 10.1021/ic101458r.
PMID:20804138
Abstract
Reaction of a heteroleptic cyclometalated iridium complex incorporating a carboxylic acid appended dipyrrin with copper acetate leads to the formation of a hexanuclear species with the paddlewheel structure.
摘要
羧酸取代二吡咯甲烷配体的杂环金属铱配合物与醋酸铜反应，生成具有桨轮结构的六核物种。
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