二烯二酸的固态三聚提供了双环丁基：通过 X 射线粉末数据和共结晶分离和结构确定得到反应物结构和产物。
A solid-state trimerisation of a diene diacid affords a bicyclobutyl: reactant structure from X-ray powder data and product separation and structure determination via co-crystallisation.
机构信息
Department of Chemistry, University of Iowa, Iowa City, Iowa, USA.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):236-8. doi: 10.1039/c0cc02204g. Epub 2010 Aug 31.
PMID:20820530
Abstract
A bicyclobutyl that bears six carboxylic acid groups results from a trimerisation of a diene diacid in the solid state. Powder X-ray diffraction and a co-crystallisation are used to solve the structure of the diene and elucidate the stereochemistry of the bicyclobutyl, respectively.
摘要
一个带有六个羧酸基团的二环丁基是由二烯二酸在固态下三聚得到的。粉末 X 射线衍射和共结晶分别用于解决二烯的结构并阐明二环丁基的立体化学。
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