Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
Chem Commun (Camb). 2010 Oct 21;46(39):7439-41. doi: 10.1039/c0cc02380a. Epub 2010 Sep 6.
Dibenzo[a,c]cyclooctatetraenes were selectively generated in good yields from the palladium-catalyzed [4+4] cyclic homocoupling of borylvinyl iodobenzene derivatives, which were prepared via the selective Suzuki-Miyaura cross-coupling of the gem-diboryl reagents with iodo compounds.
二苯并[a,c]环辛四烯通过钯催化的硼酸乙烯基碘苯衍生物的[4+4]环状同偶联反应,以良好的收率选择性生成,硼酸乙烯基碘苯衍生物是通过gem-二硼酸试剂与碘化物的选择性铃木-宫浦交叉偶联反应制备的。