Swiecicka Dorota, Garboś Sławomir
Zakład Higieny Komunalnej, Narodowy Instytut Zdrowia Publicznego-Państwowy Zakład Higieny, Warszawa.
Rocz Panstw Zakl Hig. 2010;61(2):145-50.
Silver usually exists in tap water at concentrations which are not connected with human health risk and therefore maximum admissible concentration level of this element was not established in Directive 98/83/EC concerning quality of water intended for human consumption. Disinfection of water based on generation of silver or silver compounds by electrochemical process could led to the increase of concentration of this metal in disinfected water up to level of 0.050 mg/l or higher although it should be underlined that this type of technology is not used in Poland. However in the case of application of bacteriostatic agents based on silver salts, e.g., in jug water filter systems consist of cartridges with activated carbon modified by silver compounds, this element may migrate into purified and further consumed water (applied also for preparation of coffee, tea, soup and dilution of concentrated juices) in amounts which provide essential part of daily dose of silver taken orally by human. In this work the results showing the concentration levels of silver released into purified water in the case of application of jug water filter systems with cartridges consist of activated carbon modified with silver compounds and ion exchanger were presented. Study was performed according to British Standard BS 8427:2004 which describes requirements in respect to the performance of jug water filter systems used for the domestic treatment of drinking water The concentrations of silver in challenge water purified by jug water filter systems were determined using validated method of determination of silver by inductively coupled plasma optical emission spectrometry technique (ICP-OES). In accordance to type of jug water filter systems applied grand mean of silver concentrations achieved during whole cycle of exploitations of product (including possibility of filtrations of 100 l of water) were in the range 0.0022 mg/l-0.0175 mg/l, which is not provided essential human health risk.
自来水中银的存在浓度通常与人类健康风险无关,因此在关于供人类消费的水质量的98/83/EC指令中未规定该元素的最大允许浓度水平。基于通过电化学过程生成银或银化合物的水消毒可能会导致消毒水中该金属的浓度增加至0.050毫克/升或更高水平,尽管应该强调的是,这种技术在波兰并未使用。然而,在应用基于银盐的抑菌剂时,例如在由用银化合物改性的活性炭滤芯组成的水壶滤水系统中,该元素可能会以一定量迁移到净化后的后续消费水中(也用于冲泡咖啡、茶、汤以及稀释浓缩果汁),这些量构成了人类口服银的每日剂量的重要部分。在这项工作中,展示了在使用由用银化合物改性的活性炭滤芯和离子交换器组成的水壶滤水系统时,释放到净化水中的银的浓度水平的结果。研究是根据英国标准BS 8427:2004进行的,该标准描述了用于家庭饮用水处理的水壶滤水系统的性能要求。通过电感耦合等离子体发射光谱技术(ICP - OES)采用经过验证的银测定方法,测定了水壶滤水系统净化的受试水中银的浓度。根据所应用的水壶滤水系统类型,产品整个使用周期(包括过滤100升水的可能性)内银浓度的总平均值在0.0022毫克/升 - 0.0175毫克/升范围内,这不会对人类健康构成重大风险。