调节和驱动一个氧化还原活性转子。
Tuning-up and driving a redox-active rotor.
机构信息
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):415-7. doi: 10.1039/c0cc02193h. Epub 2010 Sep 21.
PMID:20856986
Abstract
The dynamic bistable rotational behaviour of a copper(I) coordination environment can be rationally tuned with balancing the substituent size on the rotor. Such rotors are sensitive to weak interactions, and the rotation was driven by a redox reaction on a ferrocenyl moiety via reconstruction of the charge interaction between redox centres.
摘要
铜（I）配合物环境的动态双稳态旋转行为可以通过平衡转子上取代基的大小来合理调节。这些转子对弱相互作用很敏感，旋转是通过铁二茂基部分的氧化还原反应驱动的，通过重建氧化还原中心之间的电荷相互作用来实现。
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