具有氧化还原活性的二茂铁-铕偶联物的可逆发光开关。
Reversible luminescence switching of a redox-active ferrocene-europium dyad.
机构信息
Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, UK.
出版信息
J Am Chem Soc. 2011 Aug 10;133(31):11847-9. doi: 10.1021/ja203069s. Epub 2011 Jul 20.
PMID:21761827
Abstract
The copper-catalyzed cycloaddition reaction between a propargyl-appended europium complex and azidomethylferrocene yields a d-f dyad whose photophysical properties can be reversibly switched by varying the oxidation state of the ferrocene chromophore.
摘要
铜催化的丙炔基-铕配合物与叠氮甲基二茂铁之间的环加成反应生成了一个 d-f 偶联物，其光物理性质可以通过改变二茂铁发色团的氧化态来可逆地切换。
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