Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
Chem Soc Rev. 2010 Nov;39(11):4220-33. doi: 10.1039/c001965h. Epub 2010 Sep 21.
Formation of infinite structures based on the combination of metals and organic ligands, known as coordination polymers (CPs), gives rise to materials with a rich structural diversity and interesting physical and/or chemical properties. Most of the efforts towards applications of CPs have been focused on catalysis and gas-storage/separation properties. A novel approach into this field is the organization of CPs on surfaces in the search of nanomaterials with potential technological applications such as nanoelectronics, spintronics or nanosensing. Advances on surface organization of discrete metallo-organic compounds and 2D coordination polymers have been the subject of recent reviews. This tutorial review will fill up a remaining gap in the current literature: a review on one-dimensional coordination polymers on surfaces. First publications on this field appeared in 2005 and, from then, this area experienced a formidable blossoming. One of the main interests of one-dimensional systems arises from their potential use in nanoelectronics as molecular wires. This review summarizes the strategies for the isolation and structural and morphological characterization of several topologies of 1D coordination polymers on surfaces. Several parameters that affect the organization of these systems on surfaces have been taken into account from both experimental and theoretical points of view.
基于金属和有机配体组合的无限结构的形成，被称为配位聚合物（CPs），产生了具有丰富结构多样性和有趣的物理和/或化学性质的材料。CPs 的应用研究主要集中在催化和气体存储/分离性能上。在这一领域的一种新方法是在表面上组织 CPs，以寻找具有潜在技术应用的纳米材料，如纳米电子学、自旋电子学或纳米传感。离散金属有机化合物和二维配位聚合物表面组织的进展是最近综述的主题。本教程综述将填补当前文献中的一个空白：关于表面上一维配位聚合物的综述。该领域的首批出版物出现在 2005 年，从那时起，该领域经历了迅猛的发展。一维体系的主要兴趣之一源于它们在纳米电子学中作为分子导线的潜在用途。本综述总结了在表面上分离和结构及形态表征几种一维配位聚合物拓扑结构的策略。从实验和理论的角度考虑了影响这些体系在表面上组织的几个参数。
