方便获取四价铈化合物：使用碘(III)试剂进行单电子氧化。
Facile access to tetravalent cerium compounds: one-electron oxidation using iodine(III) reagents.
机构信息
Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, D-39106 Magdeburg, Germany.
出版信息
J Am Chem Soc. 2010 Oct 13;132(40):14046-7. doi: 10.1021/ja107494h.
Readily accessible and easy-to-use phenyliodine(III) dichloride, PhICl(2), has been established as an innovative and superior reagent for the one-electron oxidation of cerium(III) complexes, comprising amide, amidinate, and cyclopentadienyl derivatives. Its use allowed the successful synthesis and structural characterization of the first members of three new classes of chloro-functionalized (organo)cerium(IV) compounds, including the long sought-after Cp(3)CeCl.
易于获得且易于使用的苯碘酰氯（III）二氯化物（PhICl(2)）已被确立为一种用于铈（III）配合物单电子氧化的创新且优越的试剂，包括酰胺、酰亚胺和环戊二烯基衍生物。它的使用成功地合成并结构表征了三种新的氯官能化（有机）铈（IV）化合物的第一个成员，包括长期以来备受追捧的 Cp(3)CeCl。
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