• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

A low-spin ruthenium(IV)-oxo complex: does the spin state have an impact on the reactivity?

作者信息

Kojima Takahiko, Hirai Yuichirou, Ishizuka Tomoya, Shiota Yoshihito, Yoshizawa Kazunari, Ikemura Kenichiro, Ogura Takashi, Fukuzumi Shunichi

机构信息

Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan.

出版信息

Angew Chem Int Ed Engl. 2010 Nov 2;49(45):8449-53. doi: 10.1002/anie.201002733.

DOI:10.1002/anie.201002733
PMID:20865710
Abstract
摘要

相似文献

1
A low-spin ruthenium(IV)-oxo complex: does the spin state have an impact on the reactivity?一种低自旋钌（IV）-氧配合物：自旋态对反应活性有影响吗？
Angew Chem Int Ed Engl. 2010 Nov 2;49(45):8449-53. doi: 10.1002/anie.201002733.
2
Construction of Sn(IV) porphyrin/trinuclear ruthenium cluster dyads linked by pyridine carboxylates: photoinduced electron transfer in the Marcus inverted region.构建由吡啶羧酸连接的锡（IV）卟啉/三核钌簇偶联物：马库斯反转区中的光致电子转移。
Chemistry. 2010 Mar 22;16(12):3646-55. doi: 10.1002/chem.200902939.
3
Directing protons to the dioxygen ligand of a ruthenium(II) complex with pendent amines in the second coordination sphere.将质子导向第二配位层中带有侧链胺的钌（II）配合物的双氧配体。
Angew Chem Int Ed Engl. 2011 Nov 11;50(46):10936-9. doi: 10.1002/anie.201105266. Epub 2011 Sep 26.
4
Regulation of redox potential of a pterin derivative bound to a ruthenium(II) complex by intermolecular hydrogen bonding with nucleobases.通过与核碱基的分子间氢键作用对与钌（II）配合物结合的蝶呤衍生物的氧化还原电位进行调控。
Angew Chem Int Ed Engl. 2012 May 7;51(19):4623-7. doi: 10.1002/anie.201108827. Epub 2012 Mar 30.
5
Dithia[3.3]paracyclophane-based monometal ruthenium acetylide complexes: synthesis, characterization and substituent effects.基于[3.3]并环二噻吩的单核钌炔基配合物的合成、表征及取代基效应。
Dalton Trans. 2013 May 21;42(19):7177-89. doi: 10.1039/c3dt50234a.
6
(Eta6-arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels-Alder reaction in water.(Eta6-芳烃)钌(II)配合物和金属木瓜蛋白酶杂化物作为路易斯酸催化剂在水中进行 Diels-Alder 反应。
Dalton Trans. 2010 Jun 28;39(24):5605-7. doi: 10.1039/c001630f. Epub 2010 Apr 20.
7
Light-driven activation of the [H2O(terpy)Mn(III)-μ-(O2)-Mn(IV)(terpy)OH2] unit in a chromophore-catalyst complex.发色团 - 催化剂复合物中[H2O(terpy)Mn(III)-μ-(O2)-Mn(IV)(terpy)OH2]单元的光驱动激活
Chem Asian J. 2011 Jun 6;6(6):1335-9. doi: 10.1002/asia.201100030. Epub 2011 May 12.
8
Ligand geometry directs O-O bond-formation pathway in ruthenium-based water oxidation catalyst.配体几何结构决定钌基水氧化催化剂中氧-氧键的形成途径。
Angew Chem Int Ed Engl. 2012 Jun 11;51(24):5967-70. doi: 10.1002/anie.201201356. Epub 2012 Apr 30.
9
Conversion of oxido-bridged dinuclear ruthenium complex to dicationic dinitrosyl ruthenium complex using proton and nitric oxide: completion of NO reduction cycle.利用质子和一氧化氮将氧桥联双核钌配合物转化为二价阳离子二硝酰基钌配合物：完成 NO 还原循环。
Dalton Trans. 2011 Mar 14;40(10):2148-50. doi: 10.1039/c0dt01002b. Epub 2010 Oct 13.
10
Quinoneimido complexes of a metalloporphyrin: Isolation, X-ray crystal structures, and DFT calculations.金属卟啉的醌亚胺配合物：分离、X射线晶体结构及密度泛函理论计算
Chem Asian J. 2010 Apr 1;5(4):759-63. doi: 10.1002/asia.200900666.

引用本文的文献

1
Enhancement of Reactivity of a Ru-Oxo Complex in Oxygen-Atom-Transfer Catalysis by Hydrogen-Bonding with Amide Moieties in the Second Coordination Sphere.通过与第二配位层中的酰胺基团形成氢键增强钌-氧配合物在氧原子转移催化中的反应活性。
JACS Au. 2023 Sep 27;3(10):2813-2825. doi: 10.1021/jacsau.3c00377. eCollection 2023 Oct 23.
2
Heme compound II models in chemoselectivity and disproportionation reactions.化学选择性和歧化反应中的血红素化合物II模型
Chem Sci. 2022 Apr 12;13(19):5707-5717. doi: 10.1039/d2sc01232d. eCollection 2022 May 18.
3
Closed Shell Iron(IV) Oxo Complex with an Fe-O Triple Bond: Computational Design, Synthesis, and Reactivity.
具有铁-氧三键的闭壳层四价铁氧配合物：计算设计、合成与反应活性
Angew Chem Int Ed Engl. 2020 Dec 14;59(51):23137-23144. doi: 10.1002/anie.202009347. Epub 2020 Oct 29.
4
Crystal structure of -poly[[(μ-6-{[bis-(pyridin-2-ylmeth-yl)amino]-meth-yl}pyridine-2-carboxyl-ato)copper(II)] perchlorate aceto-nitrile monosolvate].-聚[[(μ-6-{[双-(吡啶-2-基甲基)氨基]-甲基}吡啶-2-羧酸根合)铜(II)]]高氯酸盐乙腈单溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2019 May 14;75(Pt 6):789-793. doi: 10.1107/S2056989019006285. eCollection 2019 Jun 1.
5
Formation and characterization of a reactive chromium(v)-oxo complex: mechanistic insight into hydrogen-atom transfer reactions.一种活性五价铬-氧配合物的形成与表征：对氢原子转移反应的机理洞察
Chem Sci. 2015 Feb 1;6(2):945-955. doi: 10.1039/c4sc02285h. Epub 2014 Oct 17.
6
Structure and spin state of nonheme FeO complexes depending on temperature: predictive insights from DFT calculations and experiments.非血红素FeO配合物的结构和自旋状态随温度的变化：来自密度泛函理论计算和实验的预测性见解。
Chem Sci. 2017 Aug 1;8(8):5460-5467. doi: 10.1039/c7sc01738c. Epub 2017 May 30.
7
Do Spin State and Spin Density Affect Hydrogen Atom Transfer Reactivity?自旋态和自旋密度会影响氢原子转移反应活性吗？
Chem Sci. 2014 Jan 1;5(1). doi: 10.1039/C3SC52664J.
8
Photochemical oxidation of a manganese(III) complex with oxygen and toluene derivatives to form a manganese(V)-oxo complex.光氧化锰(III)配合物与氧气和甲苯衍生物反应，生成锰(V)-氧配合物。
Inorg Chem. 2013 Dec 2;52(23):13594-604. doi: 10.1021/ic402121j. Epub 2013 Nov 12.
9
Transient Ru-methyl formate intermediates generated with bifunctional transfer hydrogenation catalysts.双功能转移氢化催化剂生成瞬态 Ru-甲酸甲酯中间体。
Proc Natl Acad Sci U S A. 2012 Feb 14;109(7):2246-50. doi: 10.1073/pnas.1118934109. Epub 2012 Feb 6.