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通过宽带介电谱测定玻璃态α弛豫动力学的温度演变

Temperature development of glassy α-relaxation dynamics determined by broadband dielectric spectroscopy.

作者信息

Lunkenheimer P, Kastner S, Köhler M, Loidl A

机构信息

Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, 86135 Augsburg, Germany.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2010 May;81(5 Pt 1):051504. doi: 10.1103/PhysRevE.81.051504. Epub 2010 May 24.

Abstract

We present the temperature dependence of α -relaxation times of 13 glass formers determined from broadband dielectric spectroscopy, also including data from aging measurements. The data sets partly cover relaxation-time ranges of up to 16 decades enabling a critical test of the validity of model predictions. For this purpose, the data are provided for electronic download. Here we employ these results to test the applicability of the Vogel-Fulcher-Tammann equation and a recently proposed new approach that was demonstrated to provide superior fits of a vast collection of viscosity data.

摘要

我们展示了通过宽带介电谱测定的13种玻璃形成体的α弛豫时间的温度依赖性,其中还包括老化测量数据。这些数据集部分涵盖了长达16个数量级的弛豫时间范围,从而能够对模型预测的有效性进行严格测试。为此,这些数据可供电子下载。在这里,我们利用这些结果来测试Vogel-Fulcher-Tammann方程以及最近提出的一种新方法的适用性,该新方法已被证明能对大量粘度数据提供更优的拟合。

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