Polymer Physics, ETH Zürich, Department of Materials, CH-8093 Zürich, Switzerland.
Phys Rev Lett. 2010 May 21;104(20):205704. doi: 10.1103/PhysRevLett.104.205704.
We give evidence of a clear structural signature of the glass transition, in terms of a static correlation length with the same dependence on the system size, which is typical of critical phenomena. Our approach is to introduce an external, static perturbation to extract the structural information from the system's response. In particular, we consider the transformation behavior of the local minima of the underlying potential energy landscape (inherent structures), under a static deformation. The finite-size scaling analysis of our numerical results indicate that the correlation length diverges at a temperature Tc, below the temperatures where the system can be equilibrated. Our numerical results are consistent with random first order theory, which predicts such a divergence with a critical exponent ν=2/3 at the Kauzmann temperature, where the extrapolated configurational entropy vanishes.
我们以与临界现象相同的系统尺寸依赖性,提供了玻璃化转变的明确结构特征的证据,这是静态相关长度的结果。我们的方法是引入外部静态扰动,从系统的响应中提取结构信息。具体来说,我们考虑在静态变形下,潜在势能景观(固有结构)的局部最小值的转变行为。我们的数值结果的有限尺寸标度分析表明,相关长度在温度 Tc 以下发散,该温度低于系统可以平衡的温度。我们的数值结果与随机一阶理论一致,该理论预测在 Kauzmann 温度下,这种发散具有临界指数 ν=2/3,此时外推的构象熵消失。