Max Planck Institute for the Physics of Complex Systems, Nöthnitzer Strasse 38, D-01187 Dresden, Germany.
Phys Rev Lett. 2010 Jun 11;104(23):233002. doi: 10.1103/PhysRevLett.104.233002. Epub 2010 Jun 7.
Inner-shell ionization of atoms and molecules leads to the creation of highly excited ionic states that often decay by electron emission. The dynamics of the decay is usually assumed to be exponential and the process is characterized by a decay rate. Here we show that in a multiply ionized cluster created by interaction with a high-intensity free-electron laser (FEL) radiation, trapping of the emitted electron by the neighboring ions changes the character of the decay dynamics qualitatively to the extent that it can become oscillatory instead of exponential. Implications of the predicted effect on Coster-Kronig and interatomic Coulombic decay processes induced by FELs are investigated.
原子和分子的内壳层电离会导致产生高度激发的离子态,这些离子态通常通过电子发射而衰减。衰减的动力学通常被假设为指数衰减,并且该过程的特征在于衰减速率。在这里,我们表明,在与高强度自由电子激光(FEL)辐射相互作用而产生的多电离团簇中,发射电子被相邻离子的捕获会使衰减动力学的性质发生定性变化,使其从指数衰减变为振荡衰减。研究了预测的 FEL 诱导的 Coster-Kronig 和原子间库仑衰减过程的影响。