高活性和可重复使用的 Pt 催化剂原位偶联氧化循环：在催化量邻氯醌存在下，使用分子氧作为末端氧化剂的脱氢氧化反应。
In situ coupled oxidation cycle catalyzed by highly active and reusable Pt-catalysts: dehydrogenative oxidation reactions in the presence of a catalytic amount of o-chloranil using molecular oxygen as the terminal oxidant.
机构信息
Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science Technology Agency (JST), Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
出版信息
Chem Commun (Camb). 2010 Nov 14;46(42):8052-4. doi: 10.1039/c0cc02865g. Epub 2010 Sep 27.
PMID:20871889
Abstract
An in situ coupled oxidation cycle that allows catalytic oxidation of a substrate with catalytic amounts of o-chloranil and novel reusable polymer-immobilized platinum nanocluster catalysts using molecular oxygen as the terminal oxidant was developed.
摘要
开发了一种原位偶联氧化循环，该循环使用邻氯醌和新型可重复使用的聚合物固载铂纳米簇催化剂，以催化量的方式催化氧化底物，并使用分子氧作为末端氧化剂。
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