通过连续的环氧化物-二醇-二酮转化，在[60]富勒烯上刻蚀两个相邻的孔。
Carving two adjacent holes on [60]fullerene through two consecutive epoxide to diol to dione transformations.
机构信息
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
出版信息
Chem Commun (Camb). 2010 Nov 28;46(44):8365-7. doi: 10.1039/c0cc02750b. Epub 2010 Oct 5.
PMID:20922262
Abstract
Repeated acid catalyzed epoxide opening and oxidation of the resulting diol with diacetoxyiodobenzene led to two 10-membered orifices on C(60) cage.
摘要
经重复酸催化开环及用过二醋酸碘苯氧化生成的二醇，导致 C(60)笼上有两个 10 元环的开口。
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