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人工氢化酶：在功能化聚吡咯基质内组装 H 簇类似物。

Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix.

机构信息

Energy Materials Laboratory, School of Chemistry, University of East Anglia, Norwich, UK NR4 7TJ.

出版信息

Chem Commun (Camb). 2010 Nov 21;46(43):8189-91. doi: 10.1039/c0cc02962a. Epub 2010 Oct 5.

DOI:10.1039/c0cc02962a
PMID:20922263
Abstract

We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

摘要

我们证明，在一个半胱氨酰-烷基铵官能化的聚吡咯内共价结合的氧化还原活性{Fe(4)S(4)}(2+)-立方烷组装体可以用二铁二硫代羰基单元进行修饰，得到一个人工氢化酶 H 簇框架，被限制在聚合物基质内。

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