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工业残渣的技术和环境长期特性——野外和实验室调查总结。

Technical and environmental long-term properties of industrial residues--summary of field and laboratory investigations.

机构信息

Swedish Geotechnical Institute (SGI), SE-581 93 Linköping, Sweden.

出版信息

Waste Manag. 2011 Jan;31(1):101-7. doi: 10.1016/j.wasman.2010.09.004. Epub 2010 Oct 6.

Abstract

In Sweden, use of industrial residues is still hindered by concern for their long-term properties. A three-year research project was therefore initiated aiming to (1) identify the crucial processes of ageing related to the usefulness of residues in roads; (2) investigate the consequences of these processes for technical and environmental properties of the residues, and (3) propose a method for accelerated ageing to predict the long-term properties. This paper gives an overview of the project methodology, a summary of the test results and references to papers where further details are given. The project, running through 2006-2008, compared naturally aged samples of two residues used as sub-bases in existing asphalt paved roads with samples of fresh residues from producers' piles. Steel slag of electric arc furnace (EAF) type and municipal solid waste incinerator (MSWI) bottom ash were chosen. The samples were thoroughly characterised in order to identify which ageing processes had been crucial. The results showed that: - Bottom ash from the pavement edge was more aged than bottom ash from the road centre. However, no difference in pH was found, instead the differences were caused by differences in water exposure. - Steel slag from the pavement edge showed traces of carbonation and leaching processes, whereas slag from the road centre was identical to fresh slag. - Water exposure to the subbase materials after ten years in an asphalt paved road was calculated to less than 0.1–0.5 litres per kg. - Ageing reactions in steel slag and MSWI bottom ash, ready for use, were too small to be verified by laboratory measurement of deformation properties under loaded conditions. An accelerated ageing test for steel slag was set up to achieve the carbonation (decrease in pH) and leaching that was observed in the pavement edge material. An accelerated ageing test for bottom ash was set up to achieve the pozzolan reactions that were observed in SEM analyses of in situ specimens. It is recommended to use uncrushed particles when properties of aged material are studied, in order to preserve the original particle surfaces.

摘要

在瑞典,人们仍然担心工业废料的长期特性,因此使用工业废料的情况受到阻碍。因此,启动了一个为期三年的研究项目,旨在:(1) 确定与残留物在道路中的有用性相关的老化关键过程;(2) 研究这些过程对残留物的技术和环境特性的影响;(3) 提出一种加速老化的方法,以预测长期特性。本文概述了项目的方法、测试结果摘要以及进一步详细信息的参考资料。该项目于 2006 年至 2008 年期间进行,将现有沥青路面中用作次基层的两种废料的自然老化样品与来自生产商料堆的新鲜废料样品进行了比较。选择了电弧炉 (EAF) 型钢渣和城市固体废物焚烧炉 (MSWI) 底灰。为了确定哪些老化过程是关键过程,对样品进行了彻底的特性分析。结果表明:- 来自路面边缘的底灰比来自道路中心的底灰老化程度更高。但是,并未发现 pH 值存在差异,而是由于水暴露的差异造成的。- 来自路面边缘的钢渣显示出碳酸化和浸出过程的痕迹,而来自道路中心的渣与新鲜渣相同。- 在沥青路面使用十年后,次基层材料的水暴露量估计不到 0.1-0.5 升/千克。- 在负载条件下,通过实验室测量变形特性,无法验证钢渣和 MSWI 底灰在使用前的老化反应。建立了钢渣加速老化试验以实现路面边缘材料中观察到的碳酸化(pH 值降低)和浸出。建立了底灰加速老化试验,以实现原位样品 SEM 分析中观察到的火山灰反应。建议在研究老化材料的性能时使用未破碎的颗粒,以保留原始颗粒表面。

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