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以污水污泥为原料制备活性炭对气态甲醛的吸附研究。

Study on activated carbon derived from sewage sludge for adsorption of gaseous formaldehyde.

机构信息

College of Environmental Science and Engineering, Hunan University, Changsha, Hunan 410082, PR China.

出版信息

Bioresour Technol. 2011 Jan;102(2):942-7. doi: 10.1016/j.biortech.2010.09.042. Epub 2010 Sep 17.

Abstract

The aim of this work is to evaluate the adsorption performances of activated carbon derived from sewage sludge (ACSS) for gaseous formaldehyde removal compared with three commercial activated carbons (CACs) using self-designing adsorption and distillation system. Formaldehyde desorption of the activated carbons for regeneration was also studied using thermogravimetric (TG) analysis. The porous structure and surface characteristics were studied using N2 adsorption and desorption isotherms, scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The results show that ACSS has excellent adsorption performance, which is overall superior to the CACs. Adsorption theory indicates that the ACSS outperforms the CACs due to its appropriate porous structure and surface chemistry characteristics for formaldehyde adsorption. The TG analysis of desorption shows that the optimum temperature to regenerate ACSS is 75°C, which is affordable and economical for recycling.

摘要

本工作旨在利用自行设计的吸附-解吸系统,评估污水污泥基活性炭(ACSS)在气态甲醛去除方面的吸附性能,并与三种商业活性炭(CACs)进行比较。还使用热重(TG)分析研究了活性炭的甲醛解吸再生性能。通过氮气吸附和脱附等温线、扫描电子显微镜(SEM)和傅里叶变换红外光谱(FTIR)研究了多孔结构和表面特性。结果表明,ACSS 具有优异的吸附性能,总体上优于 CACs。吸附理论表明,ACSS 优于 CACs,是因为其具有适当的多孔结构和表面化学特性,有利于甲醛吸附。解吸的 TG 分析表明,再生 ACSS 的最佳温度为 75°C,这对于回收来说是经济实惠的。

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