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使用各种粘结剂生产颗粒活性炭的技术发展研究

Research on the Development of Technologies for the Production of Granulated Activated Carbons Using Various Binders.

作者信息

Skoczko Iwona, Guminski Remigiusz

机构信息

Department of Technology in Environmental Engineering, Faculty of Civil and Environmental Science, Bialystok University of Technology, Wiejska 45A, 15-351 Bialystok, Poland.

出版信息

Materials (Basel). 2020 Nov 17;13(22):5180. doi: 10.3390/ma13225180.

Abstract

Activated carbons (ACs) are processed carbon-rich materials with a highly developed inner surface and significant porosity used for different media treatment in municipal and industrial plants. Activated carbon may be manufactured as powdered activated carbon (PAC), gritty activated carbon (in a form of raw angels grains) or granulated activated carbon (GAC). The production of the GAC is based on carbonaceous raw materials and various types of binders. The carbon mass is mixed with the binder and formed in cylindrical granules. The binder's recognition is in a scientific literature side-topic and still needs wider examination. For many years GAC production have been concentrated on the possibility of using sodium carboxymethylcellulose (SCMC). Therefore, the aim of the research was to develop a new binder, in the available technology of granulated activated carbon production. Such binders were tested such as: tall oil (TO), sugar beet molasses (SBM), sodium carboxymethylcellulose (SCMC), SCMC using a verified technological process and SCMC with the addition of gas tar (GT). The conducted research shows that all the quality requirements were met by activated carbons with SBM as a binder. Additionally they showed very high adsorption properties. The manufacturing process was shorter in comparison to other tested binders and more efficient.

摘要

活性炭(ACs)是经过加工的富含碳的材料,具有高度发达的内表面和显著的孔隙率,用于市政和工业工厂的不同介质处理。活性炭可以制成粉末状活性炭(PAC)、颗粒状活性炭(呈粗天使颗粒形式)或粒状活性炭(GAC)。粒状活性炭的生产基于含碳原料和各种类型的粘结剂。将碳质物料与粘结剂混合并制成圆柱形颗粒。粘结剂的识别在科学文献中是一个次要话题,仍需要更广泛的研究。多年来,粒状活性炭的生产一直集中在使用羧甲基纤维素钠(SCMC)的可能性上。因此,本研究的目的是在粒状活性炭生产的现有技术中开发一种新型粘结剂。对以下粘结剂进行了测试:妥尔油(TO)、甜菜糖蜜(SBM)、羧甲基纤维素钠(SCMC)、采用经过验证的工艺流程的SCMC以及添加了煤气焦油(GT)的SCMC。所进行的研究表明,以SBM作为粘结剂的活性炭满足了所有质量要求。此外,它们还表现出非常高的吸附性能。与其他测试粘结剂相比,其制造过程更短且效率更高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/610a/7698345/ade78b61fd73/materials-13-05180-g001.jpg

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