双氢加成过渡金属硼烷配合物：硼和过渡金属中心之间的“氢化物穿梭”过程。
Double addition of H2 to transition metal-borane complexes: a 'hydride shuttle' process between boron and transition metal centres.
机构信息
The School of Chemistry, University of Bristol, Bristol, UK.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):484-6. doi: 10.1039/c0cc02245d. Epub 2010 Oct 11.
PMID:20938529
Abstract
The addition of H(2) across a transition metal-borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.
摘要
首次报道了 H(2)在过渡金属-硼烷键上的加成，为硼烷官能团再充电到硼氢化物提供了一种机制。
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