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金纳米环三聚体:一种用于红外传感的多功能结构。

Gold nanoring trimers: a versatile structure for infrared sensing.

作者信息

Teo Siew Lang, Lin Vivian Kaixin, Marty Renaud, Large Nicolas, Llado Esther Alarcon, Arbouet Arnaud, Girard Christian, Aizpurua Javier, Tripathy Sudhiranjan, Mlayah Adnen

机构信息

Institute of Materials Research and Engineering, Agency for Science, Technology, and Research, 3 Research Link, 117602 Singapore.

出版信息

Opt Express. 2010 Oct 11;18(21):22271-82. doi: 10.1364/OE.18.022271.

Abstract

In this work we report on the observation of surface plasmon properties of periodic arrays of gold nanoring trimers fabricated by electron beam lithography. It is shown that the localized surface plasmon resonances of such gold ring trimers occur in the infrared spectral region and are strongly influenced by the nanoring geometry and their relative positions. Based on numerical simulations of the optical extinction spectra and of the electric near-field intensity maps, the resonances are assigned to surface plasmon states arising from the strong intra-trimer electromagnetic interaction. We show that the nanoring trimer configuration allows for generating infrared surface plasmon resonances associated with strongly localized electromagnetic energy, thus providing plasmonic nanoresonators well-suited for sensing and surface enhanced near-infrared Raman spectroscopy.

摘要

在这项工作中,我们报告了通过电子束光刻制备的金纳米环三聚体周期性阵列的表面等离子体特性的观察结果。结果表明,这种金环三聚体的局域表面等离子体共振发生在红外光谱区域,并且受到纳米环几何形状及其相对位置的强烈影响。基于光学消光光谱和近场电场强度图的数值模拟,这些共振被归因于三聚体内强烈的电磁相互作用产生的表面等离子体状态。我们表明,纳米环三聚体结构允许产生与强局域电磁能量相关的红外表面等离子体共振,从而提供适用于传感和表面增强近红外拉曼光谱的等离子体纳米谐振器。

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