Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China.
Inorg Chem. 2010 Nov 15;49(22):10422-6. doi: 10.1021/ic101286j. Epub 2010 Oct 14.
A fascinating 3D entangled metal-organic framework, namely, {[Co(2)(bcp)(2)]·3H(2)O}(n) (1), was obtained through the solvothermal generation of flexible and long dicarboxylate (bcp) and metal salt. The crystal structure contains a 1D metal chain with bcp ligands wrapped around it in a wavy line and features an unusual entangled topological net. Furthermore, the magnetic behavior of 1 was also studied and indicated the existence of ferromagnetic interaction and long-range ordering character.
通过溶剂热法生成柔性长二羧酸(bcp)和金属盐，得到了一个迷人的三维纠缠金属-有机骨架，即{[Co(2)(bcp)(2)]·3H(2)O}(n) (1)。晶体结构包含一个一维金属链，bcp 配体以波浪线的形式缠绕在其周围，具有不寻常的纠缠拓扑网络。此外，还研究了 1 的磁性行为，表明存在铁磁相互作用和长程有序特征。
