（13）C 魔角旋转 NMR 光谱法观察到 LOV1-C57S 光受体中的固态光 CIDNP 效应。
Solid-state photo-CIDNP effect observed in phototropin LOV1-C57S by (13)C magic-angle spinning NMR spectroscopy.
机构信息
Leiden Institute of Chemistry, Einsteinweg 55, 2300 RA Leiden, The Netherlands.
出版信息
J Am Chem Soc. 2010 Nov 10;132(44):15542-3. doi: 10.1021/ja1082969.
PMID:20958069
Abstract
Until now, the solid-state photo-CIDNP effect, discovered in 1994 by Zysmilich and McDermott, has been observed selectively in photosynthetic systems. Here we present the first observation of this effect in a nonphotosynthetic system, the blue-light photoreceptor phototropin LOV1-C57S using (13)C magic-angle spinning (MAS) NMR.
摘要
迄今为止，固态光致CIDNP 效应于 1994 年由 Zysmilich 和 McDermott 发现，仅在光合系统中选择性地观察到。在此，我们首次在非光合系统、蓝光光受体光转化 LOV1-C57S 中利用（13）C 魔角旋转（MAS）NMR 观察到该效应。
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