Faraoni A, Santucci R, Campanella L, Tranchida G, Brunori M
Department of Biochemical Sciences, University of Roma La Sapienza, Italy.
Biol Met. 1990;3(2):122-4. doi: 10.1007/BF01179518.
The electrochemical behaviour of Fe(III)-protoporphyrin IX entrapped into a cellulose triacetate membrane has been investigated by cyclic voltammetry. The physical entrapment into a solid matrix does not modify the redox properties of the entrapped hemes, which also act as efficient promoters in the electrochemistry of cytochrome c. Such a system represents a promising example of a simple 'solid-state' promoter, and stimulates further investigations in order to obtain more complex systems that may be of significance for basic and applied bioelectrochemistry.
通过循环伏安法研究了包埋在三醋酸纤维素膜中的Fe(III)-原卟啉IX的电化学行为。物理包埋在固体基质中不会改变所包埋血红素的氧化还原性质，这些血红素在细胞色素c的电化学中也起到有效的促进剂作用。这样的系统代表了一个简单“固态”促进剂的有前景的例子，并刺激了进一步的研究，以获得可能对基础和应用生物电化学具有重要意义的更复杂系统。
