Department of Chemistry, Faculty of Science and Engineering, Konan University, 8-9-1 Okamoto, Higashinada-ku, Kobe 658-8501, Japan.
J Am Chem Soc. 2010 Nov 10;132(44):15556-8. doi: 10.1021/ja1084964.
Heterobimetallic supramolecular polymers were prepared by treatment of the supramolecular polymers composed of tris(spiroborate) type molecular connecting modules with a potassium cation. On the other hand, the addition of a barium cation led to dissociation of the supramolecular polymer chain. Modulation of polymer formation was realized by the use of small metal cations as a control factor.
通过用钾阳离子处理由三（螺硼酸盐）型分子连接模块组成的超分子聚合物，制备了杂双金属超分子聚合物。另一方面，添加钡阳离子导致超分子聚合物链的解离。通过使用小金属阳离子作为控制因素，实现了聚合物形成的调节。
