• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Electron capture at the iron-oxygen centre in single crystals of oxymyoglobin studied by electron spin resonance spectroscopy.

作者信息

Symons M C, Petersen R L

出版信息

Biochim Biophys Acta. 1978 Aug 21;535(2):241-6. doi: 10.1016/0005-2795(78)90090-9.

DOI:10.1016/0005-2795(78)90090-9
PMID:209824
Abstract

Exposure of single crystals of oxy-myoglobin to 60Co gamma-rays at 77 K results in electron addition to the Fe-O2 units. The resulting ESR spectrum has been analysed to give the principal values and directions for the g-tensor of this unit. The results suggest that the dioxygen ligand is strongly tilted, the direction of tilt being close to one of the bisectors of the N-Fe-N bond angles. Possible reasons for this orientation are discussed.

摘要

相似文献

1
Electron capture at the iron-oxygen centre in single crystals of oxymyoglobin studied by electron spin resonance spectroscopy.
Biochim Biophys Acta. 1978 Aug 21;535(2):241-6. doi: 10.1016/0005-2795(78)90090-9.
2
Effect of ionizing radiation on haemoglobin: the oxy-derivative of haemoglobin Iwate.电离辐射对血红蛋白的影响：岩手血红蛋白的氧衍生物。
Proc R Soc Lond B Biol Sci. 1989 Nov 22;238(1291):103-12. doi: 10.1098/rspb.1989.0069.
3
Electron addition to the active site of Cancer magister haemocyanins. An ESR study of cu(II) centres after gamma-radiolysis.
Biochim Biophys Acta. 1978 Aug 21;535(2):247-52. doi: 10.1016/0005-2795(78)90091-0.
4
Spin-density distribution in the [FeO2]-complex. Electron spin resonance of myoglobin single crystals.
Biochim Biophys Acta. 1986 Mar 7;870(1):20-30. doi: 10.1016/0167-4838(86)90004-x.
5
Electron addition to the (FeO2) unit of oxyhaemoglobin Glycera.电子加成到含氧血红蛋白甘油的(FeO₂)单元上。
Biochim Biophys Acta. 1983 Apr 14;744(1):110-4. doi: 10.1016/0167-4838(83)90347-3.
6
Fe-O2 bonding and oxyheme structure in myoglobin.肌红蛋白中的铁-氧键和氧合血红素结构。
Proc Natl Acad Sci U S A. 1978 May;75(5):2291-5. doi: 10.1073/pnas.75.5.2291.
7
Freezing induced change in ligand orientation in oxycobalt-myoglobin.冷冻诱导氧合钴肌红蛋白中配体取向的变化。
Nature. 1980 Dec 4;288(5790):501-2. doi: 10.1038/288501a0.
8
Electron paramagnetic resonance crystallography of 17O-enriched oxycobaltomyoglobin: stereoelectronic structure of the cobalt dioxygen system.富含17O的氧合钴肌红蛋白的电子顺磁共振晶体学：钴双氧体系的立体电子结构
Proc Natl Acad Sci U S A. 1980 Mar;77(3):1235-9. doi: 10.1073/pnas.77.3.1235.
9
Single-crystal electron paramagnetic resonance studies of photolyzed oxy- and nitric oxide-cobalt myoglobins.
Biochemistry. 1982 Mar 16;21(6):1431-7. doi: 10.1021/bi00535a050.
10
End-on and side-on peroxo derivatives of non-heme iron complexes with pentadentate ligands: models for putative intermediates in biological iron/dioxygen chemistry.具有五齿配体的非血红素铁配合物的端基和侧基过氧衍生物：生物铁/双氧化学中假定中间体的模型。
Inorg Chem. 2003 Apr 21;42(8):2639-53. doi: 10.1021/ic034065p.

引用本文的文献

1
Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins.血红素蛋白和金属卟啉中的氧活化和自由基转化。
Chem Rev. 2018 Mar 14;118(5):2491-2553. doi: 10.1021/acs.chemrev.7b00373. Epub 2017 Dec 29.
2
Spectroscopic studies of the cytochrome P450 reaction mechanisms.细胞色素 P450 反应机制的光谱研究。
Biochim Biophys Acta Proteins Proteom. 2018 Jan;1866(1):178-204. doi: 10.1016/j.bbapap.2017.06.021. Epub 2017 Jun 28.
3
Resonance Raman spectroscopic studies of hydroperoxo derivatives of cobalt-substituted myoglobin.
钴取代肌红蛋白的氢过氧衍生物的共振拉曼光谱研究。
J Inorg Biochem. 2008 Oct;102(10):1952-7. doi: 10.1016/j.jinorgbio.2008.07.005. Epub 2008 Jul 23.
4
The ferric-hydroperoxo complex of chloroperoxidase.氯过氧化物酶的铁-氢过氧络合物
Biochem Biophys Res Commun. 2007 Nov 30;363(4):954-8. doi: 10.1016/j.bbrc.2007.09.085. Epub 2007 Oct 1.