Institut de Recherche Interdisciplinaire USR CNRS 3078, Université Lille Nord de France-Parc de la Haute Borne 50 Avenue de Halley, BP 70478, 59658 Villeneuve d'Ascq, Cedex, France.
Langmuir. 2010 Dec 7;26(23):18369-73. doi: 10.1021/la103097y. Epub 2010 Oct 28.
The quality of a liquid-repellent surface is quantified by both the apparent contact angle θ(0) that a sessile drop adopts on it and the value of the liquid pressure threshold the surface can withstand without being impaled by the liquid, hence maintaining a low-friction condition. We designed surfaces covered with nanowires obtained by the vapor-liquid-solid (VLS) growth technique that are able to repel most of the existing nonpolar liquids including those with very low surface tension as well as many polar liquids with moderate to high surface tension. These superomniphobic surfaces exhibit apparent contact angles ranging from 125 to 160° depending on the liquid. We tested the robustness of the surfaces against impalement by carrying out drop impact experiments. Our results show how this robustness depends on Young's contact angle θ(0) related to the surface tension of the liquid and that the orientational growth of nanowires is a favorable factor for robustness.
疏液表面的质量由固着液滴在其表面上所采用的表观接触角θ(0)和表面能够承受的液体压力阈值来定量,而不会被液体刺穿,从而保持低摩擦状态。我们设计了覆盖有通过汽-液-固(VLS)生长技术获得的纳米线的表面,这些纳米线能够排斥包括具有极低表面张力的非极性液体以及具有中等至高表面张力的许多极性液体在内的大多数现有非极性液体。这些超疏水表面的表观接触角根据液体的不同而在 125 到 160°之间变化。我们通过进行液滴冲击实验来测试表面的抗刺穿能力。我们的结果表明,这种稳健性取决于与液体表面张力有关的杨氏接触角θ(0),并且纳米线的取向生长是稳健性的有利因素。