Department of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, UK.
Chem Commun (Camb). 2011 Jan 7;47(1):517-9. doi: 10.1039/c0cc02341h. Epub 2010 Nov 1.
The simultaneous isomorphous substitution of Al(III) and P(V) ions, in an aluminophosphate framework, with redox active Co(III) and Ti(IV) metal ions, generates highly active single-site heterogeneous catalysts that exhibit considerable synergy, compared to their corresponding monometallic analogues, in the catalytic epoxidation of olefins.
在磷酸铝骨架中，同时同晶取代 Al(III) 和 P(V) 离子，并用氧化还原活性的 Co(III) 和 Ti(IV) 金属离子取代，生成了高活性的单中心多相催化剂，与相应的单核类似物相比，在烯烃的催化环氧化中表现出相当大的协同作用。
