（±）帽柱木碱 V 的全合成。
Total synthesis of (±) maoecrystal V.
机构信息
Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Shenzhen Graduate School of Peking University, Shenzhen 518055, China.
出版信息
J Am Chem Soc. 2010 Dec 1;132(47):16745-6. doi: 10.1021/ja108907x. Epub 2010 Nov 4.
PMID:21049937
Abstract
A concise first total synthesis of (±) maoecrystal V (1) is reported. The synthesis features a Wessely oxidative dearomatization of a phenol, an intramolecular Diels-Alder reaction, and a Rh-catalyzed O-H bond insertion as key steps.
摘要
报告了（±）maoecrystal V（1）的首次简洁全合成。该合成的关键步骤包括：Wessely 氧化脱芳构化酚、分子内 Diels-Alder 反应和 Rh 催化的 O-H 键插入。
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