Department of Environmental Engineering, Hanbat National University, Daejeon 305-719, Republic of Korea.
Waste Manag. 2011 Mar;31(3):523-9. doi: 10.1016/j.wasman.2010.10.009. Epub 2010 Nov 3.
Co-combustion of sewage sludge can destabilize its combustion profile due to high volatility, which results in unstable flame. We carried out fuel reforming for sewage sludge by way of carbonization at pyrolysis temperature of 300-500°C. Fuel characteristics of carbonized sludge at each temperature were analyzed. As carbonization temperature increased, fuel ratio increased, volatile content reduced, and atomic ratio relation of H/C and O/C was similar to that of lignite. The analysis result of FT-IR showed the decrease of aliphatic C-H bond and O-C bond in carbonization. In the analysis result of TG-DTG, the thermogravimetry reduction temperature of carbonized sludge (CS400) was proven to be higher than that of dried sludge, but lower than that of sub-bituminous coal. Hardgrove grindability index increased in proportion to fuel ratio increase, where the carbonized sludge value of 43-110 was similar or higher than the coal value of 49-63. As for ash deposits, slagging and fouling index were higher than that of coal. When carbonized sludge (CS400) and coal were co-combusted in 1-10% according to calorific value, slagging tendency was low in all conditions, and fouling tendency was medium or high according to the compositions of coal.
污水污泥的共燃烧会因其高挥发性而使其燃烧特性不稳定,从而导致火焰不稳定。我们通过在 300-500°C 的热解温度下对污水污泥进行碳化来进行燃料改质。分析了每个温度下碳化污泥的燃料特性。随着碳化温度的升高,燃料比增加,挥发分减少,H/C 和 O/C 的原子比关系与褐煤相似。FT-IR 的分析结果表明,碳化过程中脂肪族 C-H 键和 O-C 键减少。在 TG-DTG 的分析结果中,证明碳化污泥 (CS400) 的热重还原温度高于干燥污泥,但低于次烟煤。哈德格罗夫可磨性指数随燃料比的增加而增加,其中碳化污泥的 43-110 值与煤的 49-63 值相似或更高。至于灰分沉积物,结渣和积灰指数高于煤。当根据发热量以 1-10%的比例将碳化污泥 (CS400) 和煤共燃烧时,所有条件下的结渣倾向都较低,而根据煤的成分,结垢倾向为中或高。