Otero M, Gómez X, García A I, Morán A
Department of Chemical Engineering, Institute of Natural Resources, University of León, Avenida de Portugal 41, León, Spain.
Chemosphere. 2007 Nov;69(11):1740-50. doi: 10.1016/j.chemosphere.2007.05.077. Epub 2007 Jul 10.
Combustion of urban sewage sludge together with coal in existing infrastructures may be a sustainable management option energetically interesting for these materials, usually considered wastes. Thermogravimetric analysis was used to study the combustion of a semianthracite coal and the modifications undergone when adding a small percentage (2%, 5%, 10%) of sewage sludge. Both Differential Scanning Calorimetric analysis and Differential Thermogravimetry burning profiles showed differences between coal and sewage sludge combustion. However, the effects of adding a percentage of sewage sludge equal or smaller than 10% was hardly noticeable in terms of heat release and weight loss during the coal combustion. This was further proved by non-isothermal kinetic analysis, which was used to evaluate the Arrhenius activation energy corresponding to the co-combustion of the blends. This work shows that thermogravimetric analysis may be used as an easy rapid tool to asses the co-combustion of sewage sludge together with coal.
在现有基础设施中将城市污水污泥与煤一起燃烧,对于这些通常被视为废物的材料而言,可能是一种在能源方面颇具吸引力的可持续管理选择。热重分析用于研究一种半无烟煤的燃烧情况以及添加小比例(2%、5%、10%)污水污泥时所发生的变化。差示扫描量热分析和差示热重燃烧曲线均显示出煤和污水污泥燃烧之间的差异。然而,就煤燃烧过程中的热释放和重量损失而言,添加比例等于或小于10%的污水污泥的影响几乎不明显。非等温动力学分析进一步证明了这一点,该分析用于评估与混合物共燃烧相对应的阿累尼乌斯活化能。这项工作表明,热重分析可用作评估污水污泥与煤共燃烧情况的简便快速工具。