一种新型镍二硫烯体系的合成、表征、光谱学、电子及氧化还原性质
Synthesis, characterization, spectroscopy, electronic and redox properties of a new nickel dithiolene system.
作者信息
Basu Partha, Nigam Archana, Mogesa Benjamin, Denti Suzanne, Nemykin Victor
机构信息
Department of Chemistry and Biochemistry, Duquesne University, Pittsburgh, PA 15282.
出版信息
Inorganica Chim Acta. 2010 Oct 15;363(12):2857-2864. doi: 10.1016/j.ica.2010.04.004.
Abstract
A new dithiolene ligand with 3,5-dibromo substituted phenyl groups was designed and synthesized. The protected form of the ligand was reacted with a nickel salt providing neutral Ni(S(2)C(2)(3,5-C(6)H(3)Br(2))(2))(2) and anionic Ni(S(2)C(2)(3,5-C(6)H(3)Br(2))(2))(2) isolated as a Bu(4)N(+) salt. Both were characterized by UV-visible and IR spectroscopy and compared with the similar known molecular systems. They exhibit intense low-energy transitions that are characteristic of such systems. The electrochemical behavior of these molecules was investigated by cyclic voltammetry.
摘要
设计并合成了一种带有3,5-二溴取代苯基的新型二硫纶配体。该配体的保护形式与镍盐反应，得到中性的Ni(S₂C₂(3,5-C₆H₃Br₂)₂)₂和以Bu₄N⁺盐形式分离得到的阴离子[Ni(S₂C₂(3,5-C₆H₃Br₂)₂)₂]⁻。二者均通过紫外可见光谱和红外光谱进行了表征，并与类似的已知分子体系进行了比较。它们表现出此类体系特有的强烈低能量跃迁。通过循环伏安法研究了这些分子的电化学行为。
相似文献
1
Synthesis, characterization, spectroscopy, electronic and redox properties of a new nickel dithiolene system.一种新型镍二硫烯体系的合成、表征、光谱学、电子及氧化还原性质
Inorganica Chim Acta. 2010 Oct 15;363(12):2857-2864. doi: 10.1016/j.ica.2010.04.004.
2
Metal centered oxidation or ligand centered oxidation of metal dithiolene? Spectral, electrochemical and structural studies on a nickel-4-pyridine-1,2-dithiolate system.金属中心氧化或配体中心氧化的金属二硫烯？镍-4-吡啶-1,2-二硫醇ate 体系的光谱、电化学和结构研究。
Phys Chem Chem Phys. 2013 Mar 21;15(11):4016-23. doi: 10.1039/c3cp44054k.
3
Redox chemistry of nickel(II) complexes supported by a series of noninnocent β-diketiminate ligands.由一系列非无辜β-二酮亚胺配体支持的镍（II）配合物的氧化还原化学。
Inorg Chem. 2014 Jun 16;53(12):6159-69. doi: 10.1021/ic5006693. Epub 2014 Jun 2.
4
New series of asymmetrically substituted Bis(1,2-dithiolato)-nickel(III) complexes exhibiting near IR absorption and structural diversity.展现近红外吸收和结构多样性的新型不对称取代双（1,2 - 二硫醇根）镍（III）配合物系列。
Inorg Chem. 2008 Jun 16;47(12):5055-70. doi: 10.1021/ic701408m. Epub 2008 May 15.
5
Synthesis, electronic structure, and reactivity of strained nickel-, palladium-, and platinum-bridged [1]ferrocenophanes.桥连[1]二茂铁轮烷中镍、钯和铂的合成、电子结构和反应性。
J Am Chem Soc. 2010 Sep 29;132(38):13279-89. doi: 10.1021/ja103367e.
6
Synthesis, structures, and properties of 1,2,4,5-benzenetetrathiolate linked group 10 metal complexes.1,2,4,5-苯四硫酚连接的第 10 族金属配合物的合成、结构和性质。
Inorg Chem. 2009 Nov 16;48(22):10591-607. doi: 10.1021/ic901257s.
7
π-Bonded dithiolene complexes: synthesis, molecular structures, electrochemical behavior, and density functional theory calculations.π 键合二硫烯配合物：合成、分子结构、电化学行为及密度泛函理论计算。
Inorg Chem. 2013 Feb 4;52(3):1409-17. doi: 10.1021/ic302128q. Epub 2013 Jan 17.
8
Efficient transfer of either one or two dithiolene ligands from nickel to ruthenium: synthesis and crystal structures of [Ru(SCR=CPhS)(2)(PPh(3))] and [RuCl(2)(SCR=CPhS)(PPh(3))(2)] (R = Ph, H).高效转移一个或两个二硫烯配体从镍到钌：[Ru(SCR=CPhS)(2)(PPh(3))]和[RuCl(2)(SCR=CPhS)(PPh(3))(2)]（R = Ph，H）的合成和晶体结构。
Inorg Chem. 2009 Dec 21;48(24):11945-53. doi: 10.1021/ic9018458.
9
Synthesis, structure, spectroscopy and redox chemistry of square-planar nickel(II) complexes with tetradentate o-phenylenedioxamidates and related ligands.具有邻苯二酚二酰胺四齿配体及相关配体的平面正方形镍（II）配合物的合成、结构、光谱学及氧化还原化学
Dalton Trans. 2005 Aug 7(15):2516-26. doi: 10.1039/b502478a. Epub 2005 May 25.
10
Synthesis, spectroscopic and electrochemical studies on bis-[1,3-substituted (Cl, Br) phenyl-5-phenyl formazanato]nickel(II) complexes.
Spectrochim Acta A Mol Biomol Spectrosc. 2008 Oct;70(5):973-82. doi: 10.1016/j.saa.2007.10.010. Epub 2007 Oct 13.
引用本文的文献
1
The Impact of Ligand Oxidation State and Fold Angle on the Charge Transfer Processes of MoO-Dithione Complexes.配体氧化态和折叠角对MoO-二硫酮配合物电荷转移过程的影响
Eur J Inorg Chem. 2021 Mar 12;2021(10):914-922. doi: 10.1002/ejic.202001155. Epub 2021 Jan 18.
2
Understanding Electrochemically Induced Olefin Complexation: Towards Electrochemical Olefin-Paraffin Separations.理解电化学诱导的烯烃络合：迈向电化学烯烃 - 石蜡分离
React Chem Eng. 2024 Aug 1;9(8):2171-2179. doi: 10.1039/d4re00145a. Epub 2024 May 13.
3
Modulation between capacitor and conductor for a redox-active 2D bis(terpyridine)cobalt(II) nanosheet via anion-exchange.通过阴离子交换实现氧化还原活性二维双（三联吡啶）钴（II）纳米片在电容器与导体之间的调制。
Commun Chem. 2024 Aug 22;7(1):186. doi: 10.1038/s42004-024-01274-4.
4
Dithione, the antipodal redox partner of ene-1,2-dithiol ligands and their metal complexes.二硫酮，烯-1,2-二硫醇配体及其金属配合物的对映氧化还原伙伴。
Coord Chem Rev. 2020 May 1;409. doi: 10.1016/j.ccr.2020.213211. Epub 2020 Feb 6.
5
Design, Synthesis, and Evaluation of Extended C4-Symmetric Dirhodium Tetracarboxylate Catalysts.扩展型 C4 对称四羧酸二铑催化剂的设计、合成与评估
ACS Catal. 2022 Sep 2;12(17):10841-10848. Epub 2022 Aug 19.
6
Interligand communication in a metal mediated LL'CT system - a case study.金属介导的LL'CT体系中的配体间通讯——一个案例研究
RSC Adv. 2021 Jul 12;11(39):24381-24386. doi: 10.1039/d1ra04716g. eCollection 2021.
7
Diradical Character of Neutral Heteroleptic Bis(1,2-dithiolene) Metal Complexes: Case Study of [Pd(Metimdt)(mnt)] (Metimdt = 1,3-Dimethyl-2,4,5-trithioxoimidazolidine; mnt = 1,2-Dicyano-1,2-ethylenedithiolate).中性杂配双（1,2 - 二硫烯）金属配合物的双自由基特性：[Pd(Metimdt)(mnt)]的案例研究（Metimdt = 1,3 - 二甲基 - 2,4,5 - 三硫代咪唑烷；mnt = 1,2 - 二氰基 - 1,2 - 亚乙基二硫醇盐）
Inorg Chem. 2020 Dec 7;59(23):17385-17401. doi: 10.1021/acs.inorgchem.0c02696. Epub 2020 Nov 13.
8
Solution, Solid, and Gas Phase Studies on a Nickel Dithiolene System: Spectator Metal and Reactor Ligand.镍二硫烯体系的溶液、固相和气 相研究：旁观金属和反应配体
Inorg Chem. 2015 Aug 17;54(16):7703-16. doi: 10.1021/acs.inorgchem.5b00531. Epub 2015 Aug 5.
9
Dithiolopyranthione Synthesis, Spectroscopy and an Unusual Reactivity with DDQ.二硫代吡喃硫酮的合成、光谱学及其与2,3-二氯-5,6-二氰基-1,4-苯醌的异常反应性。
J Heterocycl Chem. 2013 Jul;50(4):879-886. doi: 10.1002/jhet.1715.
本文引用的文献
1
New series of asymmetrically substituted Bis(1,2-dithiolato)-nickel(III) complexes exhibiting near IR absorption and structural diversity.展现近红外吸收和结构多样性的新型不对称取代双（1,2 - 二硫醇根）镍（III）配合物系列。
Inorg Chem. 2008 Jun 16;47(12):5055-70. doi: 10.1021/ic701408m. Epub 2008 May 15.
2
Preparation and isolation of dithiolene thiophosphoryl molecules as stable, protected forms of dithiolene ligands.二硫纶硫代磷酰基分子的制备与分离，作为二硫纶配体的稳定、受保护形式。
Inorg Chem. 2007 Apr 16;46(8):3283-8. doi: 10.1021/ic0700203. Epub 2007 Mar 15.
3
Sulfur K-edge X-ray absorption spectroscopy as a probe of ligand-metal bond covalency: metal vs ligand oxidation in copper and nickel dithiolene complexes.硫K边X射线吸收光谱法作为配体-金属键共价性的探针：铜和镍二硫烯配合物中的金属与配体氧化
J Am Chem Soc. 2007 Feb 28;129(8):2316-26. doi: 10.1021/ja0665949. Epub 2007 Feb 2.
4
A straightforward synthesis of diverse nickel dithiolene complexes appended with hydrogen-bond donor/acceptor groups.一种直接合成带有氢键供体/受体基团的多种镍二硫纶配合物的方法。
Inorg Chem. 2005 May 16;44(10):3380-2. doi: 10.1021/ic050174n.
5
Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy.利用硫K边X射线吸收光谱法描述镍二硫纶的基态波函数
J Am Chem Soc. 2003 Jul 30;125(30):9158-69. doi: 10.1021/ja029806k.
6
A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(VI) complex under electrospray ionisation mass spectrometric conditions.在电喷雾电离质谱条件下，单氧钼（VI）配合物中氧原子转移反应的分叉途径。
Dalton Trans. 2004 Jul 7(13):1928-33. doi: 10.1039/b403964e. Epub 2004 Jun 1.
7
Functional analogue reaction systems of the DMSO reductase isoenzyme family: probable mechanism of S-oxide reduction in oxo transfer reactions mediated by bis(dithiolene)-tungsten(IV,VI) complexes.二甲基亚砜还原酶同工酶家族的功能类似反应体系：双（二硫烯）-钨（IV，VI）配合物介导的氧转移反应中S-氧化物还原的可能机制
J Am Chem Soc. 2002 Apr 24;124(16):4312-20. doi: 10.1021/ja012735p.
8
Pulsed ENDOR and ESEEM Study of [Bis(maleonitriledithiolato)nickel](-): An Investigation into the Ligand Electronic Structure.[双（马来二腈二硫醇根）镍](-)的脉冲电子核双共振和电子自旋回波包络调制研究：配体电子结构的探究
Inorg Chem. 1998 Mar 23;37(6):1361-1367. doi: 10.1021/ic9703639.
9
Nickel dithiolenes revisited: structures and electron distribution from density functional theory for the three-member electron-transfer series [Ni(S2C2Me2)2]0,1-,2-.
Inorg Chem. 2001 Aug 13;40(17):4257-62. doi: 10.1021/ic010138y.
10
A three-dimensional synthetic metallic crystal composed of single-component molecules.由单一组分分子构成的三维合成金属晶体。
Science. 2001 Jan 12;291(5502):285-7. doi: 10.1126/science.291.5502.285.
Zotero 插件