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本文引用的文献

1
New series of asymmetrically substituted Bis(1,2-dithiolato)-nickel(III) complexes exhibiting near IR absorption and structural diversity.展现近红外吸收和结构多样性的新型不对称取代双（1,2 - 二硫醇根）镍（III）配合物系列。
Inorg Chem. 2008 Jun 16;47(12):5055-70. doi: 10.1021/ic701408m. Epub 2008 May 15.
2
Preparation and isolation of dithiolene thiophosphoryl molecules as stable, protected forms of dithiolene ligands.二硫纶硫代磷酰基分子的制备与分离，作为二硫纶配体的稳定、受保护形式。
Inorg Chem. 2007 Apr 16;46(8):3283-8. doi: 10.1021/ic0700203. Epub 2007 Mar 15.
3
Sulfur K-edge X-ray absorption spectroscopy as a probe of ligand-metal bond covalency: metal vs ligand oxidation in copper and nickel dithiolene complexes.硫K边X射线吸收光谱法作为配体-金属键共价性的探针：铜和镍二硫烯配合物中的金属与配体氧化
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A straightforward synthesis of diverse nickel dithiolene complexes appended with hydrogen-bond donor/acceptor groups.一种直接合成带有氢键供体/受体基团的多种镍二硫纶配合物的方法。
Inorg Chem. 2005 May 16;44(10):3380-2. doi: 10.1021/ic050174n.
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Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy.利用硫K边X射线吸收光谱法描述镍二硫纶的基态波函数
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A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(VI) complex under electrospray ionisation mass spectrometric conditions.在电喷雾电离质谱条件下，单氧钼（VI）配合物中氧原子转移反应的分叉途径。
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Functional analogue reaction systems of the DMSO reductase isoenzyme family: probable mechanism of S-oxide reduction in oxo transfer reactions mediated by bis(dithiolene)-tungsten(IV,VI) complexes.二甲基亚砜还原酶同工酶家族的功能类似反应体系：双（二硫烯）-钨（IV，VI）配合物介导的氧转移反应中S-氧化物还原的可能机制
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Pulsed ENDOR and ESEEM Study of [Bis(maleonitriledithiolato)nickel](-): An Investigation into the Ligand Electronic Structure.[双（马来二腈二硫醇根）镍](-)的脉冲电子核双共振和电子自旋回波包络调制研究：配体电子结构的探究
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Nickel dithiolenes revisited: structures and electron distribution from density functional theory for the three-member electron-transfer series [Ni(S2C2Me2)2]0,1-,2-.
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A three-dimensional synthetic metallic crystal composed of single-component molecules.由单一组分分子构成的三维合成金属晶体。
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一种新型镍二硫烯体系的合成、表征、光谱学、电子及氧化还原性质

Synthesis, characterization, spectroscopy, electronic and redox properties of a new nickel dithiolene system.

作者信息

Basu Partha, Nigam Archana, Mogesa Benjamin, Denti Suzanne, Nemykin Victor

机构信息

Department of Chemistry and Biochemistry, Duquesne University, Pittsburgh, PA 15282.

出版信息

Inorganica Chim Acta. 2010 Oct 15;363(12):2857-2864. doi: 10.1016/j.ica.2010.04.004.

DOI:10.1016/j.ica.2010.04.004
PMID:21057604
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2967771/
Abstract

A new dithiolene ligand with 3,5-dibromo substituted phenyl groups was designed and synthesized. The protected form of the ligand was reacted with a nickel salt providing neutral Ni(S(2)C(2)(3,5-C(6)H(3)Br(2))(2))(2) and anionic Ni(S(2)C(2)(3,5-C(6)H(3)Br(2))(2))(2) isolated as a Bu(4)N(+) salt. Both were characterized by UV-visible and IR spectroscopy and compared with the similar known molecular systems. They exhibit intense low-energy transitions that are characteristic of such systems. The electrochemical behavior of these molecules was investigated by cyclic voltammetry.

摘要

设计并合成了一种带有3,5-二溴取代苯基的新型二硫纶配体。该配体的保护形式与镍盐反应，得到中性的Ni(S₂C₂(3,5-C₆H₃Br₂)₂)₂和以Bu₄N⁺盐形式分离得到的阴离子[Ni(S₂C₂(3,5-C₆H₃Br₂)₂)₂]⁻。二者均通过紫外可见光谱和红外光谱进行了表征，并与类似的已知分子体系进行了比较。它们表现出此类体系特有的强烈低能量跃迁。通过循环伏安法研究了这些分子的电化学行为。