Baudron Stéphane A, Avarvari Narcis, Batail Patrick
Chimie, Ingénierie Moléculaire et Matériaux d'Angers (CIMMA), UMR 6200 CNRS-Université d'Angers, Bâtiment K, France.
Inorg Chem. 2005 May 16;44(10):3380-2. doi: 10.1021/ic050174n.
Nickel dithiolene complexes symmetrically appended with hydrogen-bond donor/acceptor functionalities such as imide, amide, or cyano/amide groups have been synthesized by a straightforward method of wide applicability starting from one single precursor. Single-crystal X-ray structures reveal the occurrence of one type of ribbon common to all compounds that is based on a recurrent self-complementary intermolecular hydrogen-bonded ring motif linking the symmetrically substituted complexes.
通过一种从单一前体出发、适用性广泛的直接方法，合成了对称连接有氢键供体/受体官能团（如酰亚胺、酰胺或氰基/酰胺基团）的二硫纶镍配合物。单晶X射线结构表明，所有化合物都存在一种类型的带状结构，该结构基于一个重复的自互补分子间氢键环基序，连接着对称取代的配合物。
