胶束到纤维的芳香肽两亲物的生物催化超分子转化。
Micelle to fibre biocatalytic supramolecular transformation of an aromatic peptide amphiphile.
机构信息
WestCHEM, University of Strathclyde, Department of Pure and Applied Chemistry, Thomas Graham Building, 295 Cathedral Street, Glasgow, UK G1 1XL.
出版信息
Chem Commun (Camb). 2011 Jan 14;47(2):728-30. doi: 10.1039/c0cc03796f. Epub 2010 Nov 8.
PMID:21060923
Abstract
We use a range of spectroscopic methods to provide mechanistic insight into a phosphatase-driven supramolecular transformation whereby an amphiphilic peptide building block, upon dephosphorylation, switches from a solution-phase, micellar structure to a gel-phase, chiral uni-directional nanofibre morphology.
摘要
我们采用一系列光谱方法提供了对磷酸酶驱动的超分子转变的机理见解，其中亲水性肽构建块在去磷酸化后从溶液相的胶束结构转变为凝胶相的手性单方向纳米纤维形态。
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