Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
Org Lett. 2010 Dec 3;12(23):5580-3. doi: 10.1021/ol102434v. Epub 2010 Nov 10.
Pd(0)-catalyzed cross-coupling reactions of diazirines with aryl halides under microwave heating conditions afford a series of substituted olefins. A reaction mechanism involving the migratory insertion of the Pd carbene intermediate is proposed.
钯(0)催化的重氮化合物与芳基卤化物的交叉偶联反应在微波加热条件下得到一系列取代的烯烃。提出了一种涉及钯卡宾中间体迁移插入的反应机理。
