Chen J S, Chao S, Kao J S, Niu H, Chen C H
Appl Opt. 1996 Jan 1;35(1):90-6. doi: 10.1364/AO.35.000090.
We used double electron-beam coevaporation to fabricate TiO(2)-SiO(2) mixed films. The deposition process included oxygen partial pressure, substrate temperature, and deposition rate, all of which were real-time computer controlled. The optical properties of the mixed films varied from pure SiO(2) to pure TiO(2) as the composition of the films varied accordingly. X-ray diffraction showed that the mixed films all have amorphous structure with a SiO(2) content of as low as 11%. Atomic force microscopy showed that the mixed film has a smoother surface than pure TiO(2) film because of its amorphous structure.
Linear and Bruggeman's effective medium approximation models fit the experimental data better than other models.
我们采用双电子束共蒸发法制备TiO(2)-SiO(2)混合薄膜。沉积过程包括氧分压、衬底温度和沉积速率,所有这些均由计算机实时控制。随着薄膜成分相应变化,混合薄膜的光学性质从纯SiO(2)变化到纯TiO(2)。X射线衍射表明,混合薄膜均具有非晶结构,SiO(2)含量低至11%。原子力显微镜显示,由于其非晶结构,混合薄膜的表面比纯TiO(2)薄膜更光滑。
线性模型和布鲁格曼有效介质近似模型比其他模型更能拟合实验数据。