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基于[V4O12]4-二环和{Ag7}7+簇的新型丁香状银钒酸盐杂化固体的设计合成与光催化活性。

Design synthesis and photocatalytic activity of a novel lilac-like silver-vanadate hybrid solid based on dicyclic rings of [V4O12]4- with {Ag7}7+ cluster.

机构信息

Key Lab of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.

出版信息

Chem Commun (Camb). 2011 Jan 14;47(2):761-3. doi: 10.1039/c0cc02965c. Epub 2010 Nov 11.

DOI:10.1039/c0cc02965c
PMID:21069236
Abstract

An unusual two-dimensional bicyclic V(4)O(12)-based coordination polymer with a novel maximum {Ag(7)}(7+) cluster and containing five crystallographically-independent silver atoms was obtained and showed good photocatalytic activity for the degradation of methylene blue.

摘要

一种具有新颖的最大 {Ag(7)}(7+) 簇和包含五个结晶独立银原子的不寻常二维双环 V(4)O(12) 基配位聚合物被获得，并表现出良好的光催化活性，可用于降解亚甲基蓝。

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