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用于工业废物降解的BiVO纳米材料的简易水热合成

Facile hydrothermal synthesis of BiVO nanomaterials for degradation of industrial waste.

作者信息

Mansha Muhammad Salim, Iqbal Tahir, Farooq Muhammad, Riaz Khalid Nadeem, Afsheen Sumera, Sultan Muhammad Shehzad, Al-Zaqri Nabil, Warad Ismail, Masood Arslan

机构信息

Department of Physics, Faculty of Science, University of Gujrat, Hafiz Hayat Campus, Gujrat, 50700, Pakistan.

Department of Physics, University of Okara, Okara, Pakistan.

出版信息

Heliyon. 2023 May 4;9(5):e15978. doi: 10.1016/j.heliyon.2023.e15978. eCollection 2023 May.

DOI:10.1016/j.heliyon.2023.e15978
PMID:37215909
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10195907/
Abstract

Bismuth Vanadate (BiVO) has been synthesized using simple hydrothermal technique while varying the pH of concentrated HSO. With the increase of pH values (from 06 to 10), the morphology of the synthesized material tuned in the form of nano-spheres and cubes in the range from 50 to 60 nm. The lateral affect tuned the bandgap of BiVO from 2.47 eV to 2.50 eV which is significant in the context of present study. It is worth mentioning that desirous bandgap corresponds to the visible spectrum of the solar light being abundantly available and finds many applications in real life. The synthesized nanomaterial BiVO has been characterized through UV-Vis spectroscopy, X-ray diffraction, Scanning electron microscope and energy-dispersive X-ray (EDX) spectroscopy. The synthesized BiVO has been tested as photocatalyst for degradation of industrial pollutant from Leather Field Industry. Said catalyst (BiVO) successfully degraded the industrial pollutant after 3 h under solar light irradiation. Therefore, the BiVO can be regarded as potential photocatalyst for degradation of industrial waste which is highly needed.

摘要

采用简单的水热技术合成了钒酸铋（BiVO），同时改变浓HSO的pH值。随着pH值的增加（从06到10），合成材料的形态以50至60纳米范围内的纳米球和立方体形式发生变化。横向效应使BiVO的带隙从2.47电子伏特调至2.50电子伏特，这在本研究背景下具有重要意义。值得一提的是，理想的带隙对应于大量可用的太阳光的可见光谱，并在现实生活中有许多应用。合成的纳米材料BiVO已通过紫外可见光谱、X射线衍射、扫描电子显微镜和能量色散X射线（EDX）光谱进行了表征。合成的BiVO已作为光催化剂用于降解皮革工业的工业污染物进行了测试。所述催化剂（BiVO）在太阳光照射3小时后成功降解了工业污染物。因此，BiVO可被视为降解急需的工业废物的潜在光催化剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/2c854bd7d1d9/gr13.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/17cf6a51729b/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/ed26e0bd2103/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/7e2e32035a41/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/7d4f39479891/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/f5ae0c2d5f61/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/48f394c28d30/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/4c8ba76c3855/gr8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/62ac6d130225/gr9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/c5e810b4d7c3/gr10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/a02273a460aa/gr11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/b6ef0ad59184/gr12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/2c854bd7d1d9/gr13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/7ee83857e3bb/ga1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/62952b9c56b9/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/17cf6a51729b/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/ed26e0bd2103/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/7e2e32035a41/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/7d4f39479891/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/f5ae0c2d5f61/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/48f394c28d30/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/4c8ba76c3855/gr8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/62ac6d130225/gr9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/c5e810b4d7c3/gr10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/a02273a460aa/gr11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/b6ef0ad59184/gr12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/223a/10195907/2c854bd7d1d9/gr13.jpg

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