阳离子铑（I）配合物催化炔丙酯和芳基乙炔的共三聚反应，生成取代的二氢戊搭烯。
Cationic rhodium(I) complex-catalyzed cotrimerization of propargyl esters and arylacetylenes leading to substituted dihydropentalenes.
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan.
出版信息
Org Lett. 2010 Dec 3;12(23):5596-9. doi: 10.1021/ol1025266. Epub 2010 Nov 11.
PMID:21069983
Abstract
It has been established that a cationic rhodium(I)/cod complex catalyzes the cotrimerization of propargyl esters and arylacetylenes, leading to substituted dihydropentalenes, in the presence of excess cod through elimination of carboxylic acids.
摘要
业已证实，在过量 cod 的存在下，通过羧酸消除，一种阳离子铑（I）/cod 配合物可催化炔丙酯和芳基乙炔的共聚，得到取代的二氢戊二烯，生成取代的二氢戊二烯。
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