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1

A tailor-made ligand to mimic the active site of diiron enzymes: an air-oxidized high-valent Fe(III) h.s.(μ-O)2Fe(IV) h.s. species.一种定制配体模拟二铁酶的活性位点：一种空气氧化的高价态 Fe(III) h.s.(μ-O)2Fe(IV) h.s. 物种。

Chem Commun (Camb). 2011 Jan 14;47(2):695-7. doi: 10.1039/c0cc03098h. Epub 2010 Nov 19.

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Tetranuclear iron(III) complexes of an octadentate pyridine-carboxylate ligand and their catalytic activity in alkane oxidation by hydrogen peroxide.一种八齿吡啶羧酸配体的四核铁（III）配合物及其在过氧化氢氧化烷烃中的催化活性。

Dalton Trans. 2006 Jan 21(3):492-501. doi: 10.1039/b512069a. Epub 2005 Oct 10.

3

A structural and Mössbauer study of complexes with Fe(2)(micro-O(H))(2) cores: stepwise oxidation from Fe(II)(micro-OH)(2)Fe(II) through Fe(II)(micro-OH)(2)Fe(III) to Fe(III)(micro-O)(micro-OH)Fe(III).对具有Fe(2)(μ - O(H))(2)核心的配合物的结构和穆斯堡尔研究：从Fe(II)(μ - OH)(2)Fe(II)经Fe(II)(μ - OH)(2)Fe(III)到Fe(III)(μ - O)(μ - OH)Fe(III)的逐步氧化。

Inorg Chem. 2004 May 17;43(10):3067-79. doi: 10.1021/ic030296k.

4

High-valent nonheme iron-oxo species in biomimetic oxidations.仿生氧化反应中的高价非血红素铁-氧物种

J Inorg Biochem. 2006 Apr;100(4):421-33. doi: 10.1016/j.jinorgbio.2006.01.014. Epub 2006 Mar 13.

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High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.血红素和非血红素配体的高价铁（IV）-氧络合物在氧化反应中的作用。

Acc Chem Res. 2007 Jul;40(7):522-31. doi: 10.1021/ar700027f. Epub 2007 May 1.

6

Biomimetic hydrocarbon oxidation catalyzed by nonheme iron(III) complexes with peracids: evidence for an Fe(V)=O species.非血红素铁（III）配合物与过酸催化的仿生烃氧化反应：Fe（V）=O物种的证据。

Chemistry. 2007;13(33):9393-8. doi: 10.1002/chem.200700513.

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Reversible O-O bond scission of peroxodiiron(III) to high-spin oxodiiron(IV) in dioxygen activation of a diiron center with a bis-tpa dinucleating ligand as a soluble methane monooxygenase model.双三吡啶二胺核配体作为可溶性甲烷单加氧酶模型促进二铁中心中二过氧二铁(III)的 O-O 键可逆断裂生成高自旋氧代二铁(IV)以活化氧气。

J Am Chem Soc. 2012 Aug 15;134(32):13236-9. doi: 10.1021/ja306089q. Epub 2012 Aug 1.

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An EPR study of the dinuclear iron site in the soluble methane monooxygenase from Methylococcus capsulatus (Bath) reduced by one electron at 77 K: the effects of component interactions and the binding of small molecules to the diiron(III) center.对来自荚膜甲基球菌（巴斯）的可溶性甲烷单加氧酶中二核铁位点在77K下单电子还原的电子顺磁共振研究：组分相互作用及小分子与二价铁（III）中心结合的影响

Biochemistry. 1999 Mar 30;38(13):4188-97. doi: 10.1021/bi982391o.

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Stabilization of high-valent Fe(IV)S6-cores by dithiocarbamate(1-) and 1,2-dithiolate(2-) ligands in octahedral [Fe(IV)(Et2dtc)(3-n)(mnt)(n)]((n-1)-) complexes (n=0, 1, 2, 3): a spectroscopic and density functional theory computational study.高价态 Fe(IV)S6-核的稳定化作用由八面体 [Fe(IV)(Et2dtc)(3-n)(mnt)(n)]((n-1)-) 配合物中的二硫代氨基甲酸盐(1-)和 1,2-二硫醇盐(2-)配体提供：光谱和密度泛函理论计算研究。

Chemistry. 2010 Mar 22;16(12):3628-45. doi: 10.1002/chem.200903381.

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Functional mimic of dioxygen-activating centers in non-heme diiron enzymes: mechanistic implications of paramagnetic intermediates in the reactions between diiron(II) complexes and dioxygen.非血红素双铁酶中双氧激活中心的功能模拟：双铁（II）配合物与双氧反应中顺磁中间体的机理意义

J Am Chem Soc. 2002 Apr 17;124(15):3993-4007. doi: 10.1021/ja012251t.

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一种定制配体模拟二铁酶的活性位点：一种空气氧化的高价态 Fe(III) h.s.(μ-O)2Fe(IV) h.s. 物种。

A tailor-made ligand to mimic the active site of diiron enzymes: an air-oxidized high-valent Fe(III) h.s.(μ-O)2Fe(IV) h.s. species.

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