双核配合物的制备及结构研究，其包含 M(II)-OH 中心。
Preparation and structures of dinuclear complexes containing M(II)-OH centers.
机构信息
Department of Chemistry, University of California-Irvine, 1102 Natural Science II, Irvine, CA 92697, USA.
出版信息
Chem Commun (Camb). 2012 Mar 4;48(19):2546-8. doi: 10.1039/c2cc16277f. Epub 2012 Jan 30.
Abstract
The synthesis of M(II)(2) complexes (M(II)=Co, Mn) with terminal hydroxo ligands has been achieved utilizing a dinucleating ligand containing a bridging pyrazolate unit and appended (neopentyl)aminopyridyl groups. Structural studies on the complexes revealed that the M(II)-OH units are positioned in a syn-configuration, placing the hydroxo ligands in close proximity (ca. 3 Å apart), which may be a prerequisite for water oxidation.
摘要
利用含有桥连吡唑单元和附加（新戊基）氨基吡啶基的双核配体，实现了末端羟基金属配合物 M(II)(2)（M(II)=Co，Mn）的合成。对配合物的结构研究表明，M(II)-OH 单元处于顺式构型，使羟基金属配体位置非常接近（约 3 Å 分离），这可能是水氧化的前提条件。
相似文献
1
Preparation and structures of dinuclear complexes containing M(II)-OH centers.双核配合物的制备及结构研究，其包含 M(II)-OH 中心。
Chem Commun (Camb). 2012 Mar 4;48(19):2546-8. doi: 10.1039/c2cc16277f. Epub 2012 Jan 30.
2
Pyrazolate-bridging dinucleating ligands containing hydrogen-bond donors: synthesis and structure of their cobalt analogues.含氢键供体的吡唑盐桥联双核配体：其钴类似物的合成与结构
Inorg Chem. 2006 May 1;45(9):3484-6. doi: 10.1021/ic060009n.
3
Monomeric MnIII/II and FeIII/II complexes with terminal hydroxo and oxo ligands: probing reactivity via O-H bond dissociation energies.具有末端羟基和氧代配体的单体MnIII/II和FeIII/II配合物：通过O-H键解离能探究反应活性。
J Am Chem Soc. 2003 Oct 29;125(43):13234-42. doi: 10.1021/ja030149l.
4
Structural diversity in metal complexes with a dinucleating ligand containing carboxyamidopyridyl groups.含羧基酰胺基吡啶基双齿配体的金属配合物的结构多样性。
Inorg Chem. 2011 Sep 5;50(17):7922-4. doi: 10.1021/ic200881t. Epub 2011 Jul 27.
5
Dinuclear seven-coordinate Mn(II) complexes: effect of manganese(II)-hydroxo species on water exchange and superoxide dismutase activity.双核七配位 Mn(II) 配合物：Mn(II)-羟物种对水交换和超氧化物歧化酶活性的影响。
Inorg Chem. 2013 Jan 7;52(1):222-36. doi: 10.1021/ic301714d. Epub 2012 Dec 20.
6
Structural diversity in manganese, iron and cobalt complexes of the ditopic 1,2-bis(2,2'-bipyridyl-6-yl)ethyne ligand and observation of epoxidation and catalase activity of manganese compounds.双齿配体 1,2-双(2,2'-联吡啶-6-基)乙炔的锰、铁和钴配合物的结构多样性及锰化合物的环氧化和过氧化氢酶活性观察。
Dalton Trans. 2010 Aug 21;39(31):7266-75. doi: 10.1039/b925129d. Epub 2010 Jun 25.
7
Assembly and properties of heterobimetallic Co(II/III)/Ca(II) complexes with aquo and hydroxo ligands.偕同水和羟基数配体的异双核 Co(II/III)/Ca(II) 配合物的组装与性质。
J Am Chem Soc. 2012 Oct 24;134(42):17526-35. doi: 10.1021/ja304525n. Epub 2012 Oct 15.
8
Acetonitrile hydration and ethyl acetate hydrolysis by pyrazolate-bridged cobalt(II) dimers containing hydrogen-bond donors.含氢键供体的吡唑盐桥联钴（II）二聚体催化乙腈水合和乙酸乙酯水解反应
Inorg Chem. 2007 Nov 26;46(24):10120-32. doi: 10.1021/ic700685g. Epub 2007 Nov 1.
9
Studies of a dinuclear manganese complex with phenoxo and bis-acetato bridging in the Mn2(II,II) and Mn2(II,III) states: Coordination structural shifts and oxidation state control in bridged dinuclear complexes.关于处于Mn2(II,II)和Mn2(II,III)状态下具有苯氧基和双乙酸酯桥联的双核锰配合物的研究：桥联双核配合物中的配位结构转变和氧化态控制
Inorg Chem. 2006 Apr 3;45(7):3023-33. doi: 10.1021/ic060039q.
10
"Bridging hydroxide effect" on mu-carboxylato coordination and electrochemical potentials of bimetallic centers: Mn2(II,II) and Mn2(III,III) complexes as functional models of dimanganese catalases.“桥连氢氧化物效应”对双金属中心的μ-羧基配位及电化学势的影响：以Mn2(II,II)和Mn2(III,III)配合物作为双锰过氧化氢酶的功能模型
Inorg Chem. 2000 Jul 10;39(14):3009-19. doi: 10.1021/ic9911769.
引用本文的文献
1
A Co-Hydroxide Complex That Converts Directly to a Co-Acetamide during Catalytic Nitrile Hydration.一种在催化腈水合过程中直接转化为钴乙酰胺的共氢氧化物配合物。
Inorg Chem. 2024 Apr 29;63(17):7896-7902. doi: 10.1021/acs.inorgchem.4c00754. Epub 2024 Apr 12.
2
Stepwise assembly of heterobimetallic complexes: synthesis, structure, and physical properties.分步组装杂双金属配合物：合成、结构和物理性质。
Dalton Trans. 2021 Jun 15;50(23):8111-8119. doi: 10.1039/d1dt01021b.
3
Analysis of the Puzzling Exchange-Coupling Constants in a Series of Heterobimetallic Complexes.一系列异双金属配合物中令人费解的交换耦合常数分析
Inorg Chem. 2019 Jul 15;58(14):9150-9160. doi: 10.1021/acs.inorgchem.9b00757. Epub 2019 Jun 26.
4
Modular bimetallic complexes with a sulfonamido-based ligand.基于磺酰胺的模块化双金属配合物。
Dalton Trans. 2018 Sep 11;47(35):12362-12372. doi: 10.1039/c8dt02455c.
5
Models for Unsymmetrical Active Sites in Metalloproteins: Structural, Redox, and Magnetic Properties of Bimetallic Complexes with M-(μ-OH)-Fe Cores.金属蛋白中非对称活性位点的模型：具有M-(μ-OH)-Fe核心的双金属配合物的结构、氧化还原和磁性性质
Inorg Chem. 2017 Nov 20;56(22):14118-14128. doi: 10.1021/acs.inorgchem.7b02230. Epub 2017 Nov 7.
6
Tetranuclear Manganese Models of the OEC Displaying Hydrogen Bonding Interactions: Application to Electrocatalytic Water Oxidation to Hydrogen Peroxide.四核锰模型展示 OEC 的氢键相互作用：在电催化水氧化为过氧化氢中的应用。
J Am Chem Soc. 2017 Jul 12;139(27):9108-9111. doi: 10.1021/jacs.7b03044. Epub 2017 Jun 27.
本文引用的文献
1
Synthesis, Structure, and Spectroscopic Properties of [Fe (tnpa)(OH)(PhCOO)]ClO : A Model Complex for an Active Form of Soybean Lipoxygenase-1.[Fe(tnpa)(OH)(PhCOO)]ClO的合成、结构及光谱性质：大豆脂氧合酶-1活性形式的模型配合物
Angew Chem Int Ed Engl. 1998 Aug 17;37(15):2102-2104. doi: 10.1002/(SICI)1521-3773(19980817)37:15<2102::AID-ANIE2102>3.0.CO;2-A.
2
Structural diversity in metal complexes with a dinucleating ligand containing carboxyamidopyridyl groups.含羧基酰胺基吡啶基双齿配体的金属配合物的结构多样性。
Inorg Chem. 2011 Sep 5;50(17):7922-4. doi: 10.1021/ic200881t. Epub 2011 Jul 27.
3
Encapsulation of a magnesium hydroxide cubane by a bowl-shaped polypyrrolic Schiff base macrocycle.镁羟基金刚烷被碗状聚吡咯希夫碱大环包裹。
J Am Chem Soc. 2011 May 18;133(19):7320-3. doi: 10.1021/ja201630b. Epub 2011 Apr 25.
4
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å.氧气产生光合作用 II 系统在 1.9 Å 分辨率下的晶体结构。
Nature. 2011 May 5;473(7345):55-60. doi: 10.1038/nature09913. Epub 2011 Apr 17.
5
Catalytic reduction of dioxygen to water with a monomeric manganese complex at room temperature.室温下单锰配合物催化还原氧气为水。
J Am Chem Soc. 2011 Apr 20;133(15):5810-7. doi: 10.1021/ja106564a. Epub 2011 Mar 22.
6
A tailor-made ligand to mimic the active site of diiron enzymes: an air-oxidized high-valent Fe(III) h.s.(μ-O)2Fe(IV) h.s. species.一种定制配体模拟二铁酶的活性位点：一种空气氧化的高价态 Fe(III) h.s.(μ-O)2Fe(IV) h.s. 物种。
Chem Commun (Camb). 2011 Jan 14;47(2):695-7. doi: 10.1039/c0cc03098h. Epub 2010 Nov 19.
7
Mechanistic studies of the oxygen evolution reaction by a cobalt-phosphate catalyst at neutral pH.钴磷酸盐催化剂在中性 pH 下的氧析出反应的机理研究。
J Am Chem Soc. 2010 Nov 24;132(46):16501-9. doi: 10.1021/ja106102b. Epub 2010 Oct 26.
8
Role of the secondary coordination sphere in metal-mediated dioxygen activation.二次配位球在金属介导的氧气活化中的作用。
Inorg Chem. 2010 Apr 19;49(8):3646-60. doi: 10.1021/ic901550k.
9
Cofacial dicobalt complex of a binucleating hexacarboxamide cryptand ligand.双核六羧基穴醚配体的面心双钴配合物。
Inorg Chem. 2010 Apr 19;49(8):3697-9. doi: 10.1021/ic100395a.
10
O2-dependent aliphatic carbon-carbon bond cleavage reactivity in a Ni(II) enolate complex having a hydrogen bond donor microenvironment; comparison with a hydrophobic analogue.具有氢键供体微环境的 Ni(II)烯醇化物配合物中的 O2 依赖性脂肪族碳-碳键断裂反应性；与疏水性类似物的比较。
Inorg Chem. 2010 Feb 1;49(3):1071-81. doi: 10.1021/ic901981y.
Zotero 插件