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Synthesis, Structure, and Spectroscopic Properties of [Fe (tnpa)(OH)(PhCOO)]ClO : A Model Complex for an Active Form of Soybean Lipoxygenase-1.[Fe(tnpa)(OH)(PhCOO)]ClO的合成、结构及光谱性质：大豆脂氧合酶-1活性形式的模型配合物
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2
Structural diversity in metal complexes with a dinucleating ligand containing carboxyamidopyridyl groups.含羧基酰胺基吡啶基双齿配体的金属配合物的结构多样性。
Inorg Chem. 2011 Sep 5;50(17):7922-4. doi: 10.1021/ic200881t. Epub 2011 Jul 27.
3
Encapsulation of a magnesium hydroxide cubane by a bowl-shaped polypyrrolic Schiff base macrocycle.镁羟基金刚烷被碗状聚吡咯希夫碱大环包裹。
J Am Chem Soc. 2011 May 18;133(19):7320-3. doi: 10.1021/ja201630b. Epub 2011 Apr 25.
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Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å.氧气产生光合作用 II 系统在 1.9 Å 分辨率下的晶体结构。
Nature. 2011 May 5;473(7345):55-60. doi: 10.1038/nature09913. Epub 2011 Apr 17.
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双核配合物的制备及结构研究，其包含 M(II)-OH 中心。

Preparation and structures of dinuclear complexes containing M(II)-OH centers.

机构信息

Department of Chemistry, University of California-Irvine, 1102 Natural Science II, Irvine, CA 92697, USA.

出版信息

Chem Commun (Camb). 2012 Mar 4;48(19):2546-8. doi: 10.1039/c2cc16277f. Epub 2012 Jan 30.

DOI:10.1039/c2cc16277f
PMID:22288074
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3777269/
Abstract

The synthesis of M(II)(2) complexes (M(II)=Co, Mn) with terminal hydroxo ligands has been achieved utilizing a dinucleating ligand containing a bridging pyrazolate unit and appended (neopentyl)aminopyridyl groups. Structural studies on the complexes revealed that the M(II)-OH units are positioned in a syn-configuration, placing the hydroxo ligands in close proximity (ca. 3 Å apart), which may be a prerequisite for water oxidation.

摘要

利用含有桥连吡唑单元和附加（新戊基）氨基吡啶基的双核配体，实现了末端羟基金属配合物 M(II)(2)（M(II)=Co，Mn）的合成。对配合物的结构研究表明，M(II)-OH 单元处于顺式构型，使羟基金属配体位置非常接近（约 3 Å 分离），这可能是水氧化的前提条件。