Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA, USA.
Nanoscale. 2011 Jan;3(1):86-95. doi: 10.1039/c0nr00600a. Epub 2010 Nov 22.
The current status of graphene edge fabrication and characterization is reviewed in detail. We first compare different fabrication methods, including the chemical vapor deposition method, various ways of unzipping carbon nanotubes, and lithographic methods. We then summarize the different edge/ribbon structures that have been produced experimentally or predicted theoretically. We discuss different characterization tools, such as transmission electron microscopy and Raman spectroscopy, that are currently used for evaluating the edge quality as well as the atomic structures. Finally, a detailed discussion of defective and folded edges is also presented. Considering the short history of graphene edge research, the progress has been impressive, and many further advances in this field are anticipated.
详细回顾了石墨烯边缘制备和表征的现状。我们首先比较了不同的制备方法,包括化学气相沉积法、各种碳纳米管的解拉链方法和光刻方法。然后,我们总结了实验上已经制备或理论上预测的不同边缘/条带结构。我们讨论了目前用于评估边缘质量和原子结构的不同表征工具,如透射电子显微镜和拉曼光谱。最后,还详细讨论了有缺陷和折叠的边缘。考虑到石墨烯边缘研究的短暂历史,这方面的进展令人印象深刻,预计该领域还会有更多的进展。