Wu Dezhi, Huang Xiaoping, Lai Xiting, Sun Daoheng, Lin Liwei
Department of Mechanical and Electrical Engineering, Xiamen University, Xiamen 361005, P. R. China.
J Nanosci Nanotechnol. 2010 Jul;10(7):4221-6. doi: 10.1166/jnn.2010.2194.
High throughput production of nanofibers by means of "Tip-less Electrospinning" (TLES) has been demonstrated using a circular cylinder as the emitting electrode. Electrohydrodynamics instabilities on a thin liquid film under high electrical field can generate artificial liquid jets for the TLES process. Experimental results have shown that the yield of poly(ethylene oxide) nanofibers can be more than 260 times in weight as compared with a single-jet electrospinning process. Parameters affecting the TLES process including applied voltage, polymer solution concentration, electrode-to-substrate distance and the thickness of liquid films have been characterized. As such, TLES has potential for high-throughput, massive production of electrospun nanofibers.
通过使用圆柱体作为发射电极,已经证明了借助“无针静电纺丝”(TLES)可实现纳米纤维的高通量生产。在高电场下,薄液膜上的电流体动力学不稳定性可为TLES过程产生人造液滴。实验结果表明,与单射流静电纺丝工艺相比,聚环氧乙烷纳米纤维的产量在重量上可提高260倍以上。已经对影响TLES过程的参数进行了表征,这些参数包括施加电压、聚合物溶液浓度、电极到基底的距离以及液膜厚度。因此,TLES在高通量、大规模生产电纺纳米纤维方面具有潜力。