Department of Physics, Faculty of Science, University of Ostrava, 30. dubna 22, 701 03 Ostrava, Czech Republic.
J Chem Phys. 2010 Dec 7;133(21):214302. doi: 10.1063/1.3507873.
Photodissociation of the ionized argon pentamer, Ar(5)(+), is studied using an extended diatomics-in-molecules interaction model with the inclusion of the spin-orbit coupling and various dynamical approaches. A thorough comparison with the experimental data available in the literature is presented, including photofragment abundances and their kinetic and internal energy distributions. New predictions are reported for ultraviolet photoexcitation energies, a range that has not been studied before either experimentally or theoretically.
使用扩展的双原子分子相互作用模型，并包括自旋轨道耦合和各种动力学方法，研究了离子氩五聚体 Ar(5)(+)的光解。与文献中可用的实验数据进行了彻底的比较，包括光碎片丰度及其动力学和内部能量分布。报告了新的紫外光激发能量预测，这是一个以前无论是实验上还是理论上都没有研究过的范围。
