Department of Chemical Engineering, Tallinn University of Technology, Ehitajate tee 5, Tallinn 19086, Estonia.
Chemosphere. 2011 Feb;82(8):1196-201. doi: 10.1016/j.chemosphere.2010.11.053. Epub 2010 Dec 13.
Calcium and magnesium peroxides were applied for the treatment of soil contaminated by polychlorinated biphenyls-containing electrical insulating oil (Aroclor 1016). The removal of PCB-containing electrical insulating oil was achieved with the addition of either calcium peroxide or magnesium peroxide alone and dependent on dosages of the chemical. A 21-d treatment of 60% watered soil with the moderate addition (chemical/oil weight ratio of 0.005/1) of either calcium peroxide or magnesium peroxide resulted in nearly complete (96 ± 2%) oil removal, unsubstantial increase in soil pH and almost no changes in oxygen consumption and dehydrogenase activity, making it suitable for the soil decontamination.
过钙和过镁被应用于处理含多氯联苯的电力设备油(Aroclor 1016)污染的土壤。单独添加过钙或过镁,可去除含多氯联苯的电力设备油,且去除效果取决于化学物质的剂量。在 21 天的处理时间内,向 60%的湿润土壤中适度添加(化学物质/油的重量比为 0.005/1)过钙或过镁,可实现近 100%(96±2%)的除油效果,土壤 pH 值的增加微乎其微,耗氧量和脱氢酶活性几乎没有变化,非常适合土壤去污。