金配合物催化的叔胺的氧化α-氰化反应。
Gold-complexes catalyzed oxidative α-cyanation of tertiary amines.
机构信息
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
出版信息
Chem Commun (Camb). 2011 Feb 28;47(8):2354-6. doi: 10.1039/c0cc03844j. Epub 2010 Dec 13.
PMID:21152609
Abstract
Oxidative α-cyanation of tertiary amines is catalyzed by gold complexes with trimethylsilyl cyanide to afford the corresponding α-aminonitriles in the presence of tert-butyl hydroperoxide in good to excellent yields under acid-free conditions at room temperature.
摘要
金配合物催化三甲基硅基氰化物对叔胺进行氧化α-氰化反应，在无酸条件下，以叔丁基过氧化氢为氧化剂，室温下反应，以良好到优秀的收率得到相应的α-氨基腈。
Zotero 插件