以硫氰酸钾作为“CN”试剂，通过可见光诱导的芳基四氢异喹啉氧化氰化反应合成α-氨基腈。
Oxidative cyanation of -aryltetrahydroisoquinoline induced by visible light for the synthesis of α-aminonitrile using potassium thiocyanate as a "CN" agent.
作者信息
Yi Bing, Yan Ning, Yi Niannian, Xie Yanjun, Wen Xiaoyong, Au Chak-Tong, Lan Donghui
机构信息
Hunan Province Key Laboratory of Environmental Catalysis and Waste Rechemistry, College of Chemistry and Chemical Engineering, Hunan Institute of Engineering Xiangtan 411104 P. R. China
出版信息
RSC Adv. 2019 Sep 19;9(51):29721-29725. doi: 10.1039/c9ra06120g. eCollection 2019 Sep 18.
A novel method for the synthesis of α-aminonitrile through visible-light-induced oxidative cyanation of -aryltetrahydroisoquinoline with potassium thiocyanate has been developed. The process does not require the use of a photocatalyst, transition metal reagent, strong oxidizing agent, or toxic cyano-containing compound, which makes the reaction simple and green.
已开发出一种通过可见光诱导的硫氰酸钾对芳基四氢异喹啉进行氧化氰化反应来合成α-氨基腈的新方法。该过程不需要使用光催化剂、过渡金属试剂、强氧化剂或有毒的含氰化合物，这使得反应简单且绿色环保。
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