Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India.
Inorg Chem. 2011 Jan 17;50(2):400-2. doi: 10.1021/ic101232u. Epub 2010 Dec 16.
A 2D flexible metal-organic porous solid, {Ni(1,3-adc)(bpp)(H2O)2(EtOH)}n (1), has been synthesized using flexible organic linkers. The desolvated framework, {[Ni(1,3-adc)(bpp)]}n (1'), undergoes structural contraction and exhibits double-step hysteretic adsorption for CO2, H2O, and MeOH and single-step gate-opening behavior with EtOH. These observations are correlated with the effect of the polarity and window dimension of the pore to the corresponding adsorbate molecules.
一种二维柔性金属有机多孔固体，[{Ni(1,3-adc)(bpp)(H2O)2}(H2O)(EtOH)]n(1)，使用柔性有机配体合成。脱溶剂骨架，[{Ni(1,3-adc)(bpp)]}n(1')，经历结构收缩并表现出 CO2、H2O 和 MeOH 的双重滞后吸附以及 EtOH 的单步门控行为。这些观察结果与孔的极性和窗口尺寸对相应吸附物分子的影响有关。
