(1S,5R,6S)-5-叠氮基-6-苄氧基环己-2-烯-1-醇的简便合成方法。
A facile synthesis of (1S,5R,6S)-5-azido-6-benzyloxycyclohex-2-en-1-ol.
作者信息
Tanaka Takanori, Tan Qitao, Iwanaga Kazunari, Hayashi Masahiko
机构信息
Department of Chemistry, Graduate School of Science, Kobe University, Kobe 657-8501, Japan.
出版信息
Carbohydr Res. 2011 Feb 1;346(2):340-2. doi: 10.1016/j.carres.2010.11.012. Epub 2010 Nov 19.
PMID:21163468
Abstract
A facile and short synthesis of (1S,5R,6S)-5-azido-6-benzyloxycyclohex-2-en-1-ol (1) has been achieved in high yield starting from 4,5-epoxycyclohex-1-ene by using a catalytic asymmetric allylic oxidation reaction.
摘要
通过催化不对称烯丙基氧化反应，以4,5-环氧环己-1-烯为起始原料，简便快捷地高产率合成了(1S,5R,6S)-5-叠氮基-6-苄氧基环己-2-烯-1-醇(1)。
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