Melville Laboratory for Polymer Synthesis, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.
J Am Chem Soc. 2011 Feb 2;133(4):683-5. doi: 10.1021/ja108541z. Epub 2010 Dec 20.
A new zwitterionic conjugated polyelectrolyte without free counterions has been used as an electron injection material in polymer light-emitting diodes. Both the efficiency and maximum brightness were considerably improved in comparison with standard Ca cathode devices. The devices showed very fast response times, indicating that the improved performance is, in addition to hole blocking, due to dipoles at the cathode interface, which facilitate electron injection.
一种新型的无游离抗衡离子的两性离子共轭聚合物电解质被用作聚合物发光二极管中的电子注入材料。与标准的 Ca 阴极器件相比,其效率和最大亮度都得到了显著提高。这些器件表现出非常快的响应时间,这表明除了空穴阻挡作用之外,改善性能还归因于阴极界面的偶极子,这有利于电子注入。